Registration Dossier
Registration Dossier
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EC number: 203-623-8 | CAS number: 108-86-1
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
After inhalation: fresh air.
After skin contact: wash off with plenty of water. Remove contaminated clothing.
After eye contact: rinse out with plenty of water with the eyelid held wide open. Call in ophthalmologist if necessary.
After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary failure possible after aspiration of vomit. Call a physician immediately.
Most important symptoms and effects, both acute and delayed
irritant effects
agitation, Diarrhoea, Vomiting, Headache, narcosis
Indication of any immediate medical attention and special treatment needed
No information available.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media
Water, Foam, Carbon dioxide (CO2), Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture
Combustible
Vapours are heavier than air and may spread along floors.
Pay attention to flashback.
Forms explosive mixtures with air at elevated temperatures.
Development of hazardous combustion gases or vapours possible in the event of fire.
Fire may cause evolution of:
hydrogen bromide
Advice for firefighters
Special protective equipment for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders: Protective equipment see SDS section 8.
Environmental precautions
Do not let product enter drains. Risk of explosion.
Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see SDS sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area.
Reference to other sections
Indications about waste treatment see SDS section 13.
Handling and storage
Precautions for safe handling
Advice on safe handling
Observe label precautions.
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Conditions for safe storage, including any incompatibilities
Storage conditions
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.
Store at +15°C to +25°C.
Specific end use(s)
Apart from the uses mentioned in SDS section 1.2 no other specific uses are stipulated.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Exposure controls
Engineering measures
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.
See SDS section 7.1.
Individual protection measures
Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye/face protection
Safety glasses
Hand protection
full contact:
Glove material:
Viton (R)
Glove thickness:
0,70 mm
Break through time:
> 480 min
splash contact:
Glove material:
butyl-rubber
Glove thickness:
0,70 mm
Break through time:
> 30 min
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 890 Vitoject® (full contact), KCL 898 Butoject® (splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet<(>,<)> supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves.
Other protective equipment
Flame retardant antistatic protective clothing
Respiratory protection
required when vapours/aerosols are generated.
Recommended Filter type: Filter A-(P2)
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Environmental exposure controls
Do not let product enter drains.
Risk of explosion.
Stability and reactivity
Reactivity
Vapour/air-mixtures are explosive at intense warming.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
Violent reactions possible with:
Oxidizing agents, peroxi compounds, Alkali metals, Alkaline earth metals
Conditions to avoid
Heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
Incompatible materials
no information available
Hazardous decomposition products
in the event of fire: See SDS section 5
Disposal considerations
Waste treatment methods
contact us there if you have questions.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
