Registration Dossier
Registration Dossier
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EC number: 204-288-0 | CAS number: 118-93-4
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Rinse mouth and then drink plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: No significant symptoms are expected due to the non-classification of the product.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Symptomatic treatment (decontamination, vital functions).
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
5.2. Special hazards arising from the substance or mixture
carbon monoxide, Carbon dioxide
The substances/groups of substances mentioned can be released in case of fire.
5.3. Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing. Use personal protective clothing.
6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
For small amounts: Contain with absorbent material (e.g. sand, silica gel, acid binder, general purpose binder, sawdust). Dispose of absorbed material in accordance with regulations.
For large amounts: Contain with absorbent material (e.g. sand, silica gel, acid binder, general purpose binder, sawdust). Dispose of absorbed material in accordance with regulations.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Handling and storage
7.1. Precautions for safe handling
Protection against fire and explosion:
No special precautions necessary.
7.2. Conditions for safe storage, including any incompatibilities
Suitable materials for containers: Stainless steel 1.4541, Stainless steel 1.4571, glass, High density polyethylene (HDPE), Low density polyethylene (LDPE), Steel with polyethylene liner
Further information on storage conditions: Keep container tightly closed. Protect contents from the effects of light.
Storage class according to TRGS 510 (originally VCI, Germany): (10) Combustible liquids
7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
The surveillance of the workplace by exposure measurements may be necessary, in order to proof the efficiency of safety measures, for example ventilation or the need of respiratory protection. Since this requires a specific competency, only accredited laboratories should be contracted. Regarding suitable methods for inhalative exposure assessment the European Standards EN 482, 689 and 14042 are to be considered. In addition the TRGS 402 has to be observed in Germany.
108-95-2: phenol
STEL value 16 mg/m3 ; 4 ppm (OEL (EU))
indicative
TWA value 8 mg/m3 ; 2 ppm (OEL (EU))
indicative
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
Short Term Exposure Classification: (TRGS 900 (DE)), Vapor and aerosol
Category II: Substances with a resorptive effect
OEL 8 mg/m3 ; 2 ppm (TRGS 900 (DE)), Vapor and aerosol
Ceiling limit value/factor: 2
Sum of vapors and aerosols.
Skin Designation (TRGS 900 (DE)), Vapor and aerosol
The substance can be absorbed through the skin.
Components with biological limit values
108-95-2: phenol
TRGS 903 (DE)
Determinant: Phenol with hydrolysis
Biological Specimen: Creatinine in urine
Sampling time: End of shift
Concentration: 120 mg/g Creatinine
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
No body protection required if used for intended purpose and satisfying generally accepted industrial hygiene rules.
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. When using, do not eat, drink or smoke. Take off immediately all contaminated clothing. Store work clothing separately.
Environmental exposure controls
For information regarding environmental exposure controls, see Section 6.
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated.
10.2. Chemical stability
The product is chemically stable.
10.3. Possibility of hazardous reactions
No hazardous reactions if stored and handled as prescribed/indicated.
The product is chemically stable.
10.4. Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.
10.5. Incompatible materials
Substances to avoid:
No data available.
10.6. Hazardous decomposition products
Possible thermal decomposition products:
Carbon dioxide, carbon monoxide
Disposal considerations
13.1. Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
Contaminated packaging:
Uncleaned empties should be disposed of in the same manner as the contents.
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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