Registration Dossier
Registration Dossier
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EC number: 221-717-7 | CAS number: 3209-22-1
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General advice: Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled:
If unconscious, place in recovery position and seek medical advice.
If symptoms persist, call a physician.
In case of skin contact:
Wash skin immediately with plenty of water and soap. Subse-quent cleansing with polyethyleneglycol 400, then again with water and soap.
In case of blueness of lips, skin or nails (cyanosis) let the per-son breathe oxygen.
If on clothes, remove clothes.
In case of eye contact:
Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed:
Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Risks:Toxic if swallowed or if inhaled.
Harmful in contact with skin.
May cause an allergic skin reaction
Indication of any immediate medical attention and special treatment needed
Treatment:Elementary aid, decontamination, symptomatic treatment and depending on the formation of methaemoglobin: intravenous administration of toluidine blue or other redox dyes according to dosage specifications plus ascorbic acid.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:Use water spray, alcohol-resistant foam, dry chemical or car-bon dioxide.
Unsuitable extinguishing media:High volume water jet
Special hazards arising from the substance or mixture
Hazardous combustion prod-ucts:
Carbon dioxide (CO2)
Carbon monoxide
Nitrogen oxides (NOx)
Halogenated compounds
Advice for firefighters
Special protective equipment for firefighters:Wear self-contained breathing apparatus for firefighting if nec-essary.
Further information:
Cool closed containers exposed to fire with water.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions:
Use personal protective equipment.
Avoid dust formation.
Do not breathe vapours/dust.
Environmental precautions
Environmental precautions:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up
Methods for cleaning up:Vacuum or sweep up material and place in a designated, labelled waste container.
Dispose of wastes in an approved waste disposal facility.
Handling and storage
Precautions for safe handling
Technical measures:
The product is registered with strictly controlled conditions as defined in Article 17(3) or 18(4) of regulation (EC) no. 1907/2006 (REACH Regulation) and must therefore be han-dled as such. Refer to the industry guidance prepared by Concawe/Cefic/EFCG for advice on the confirmation of strictly controlled conditions.
Advice on safe handling:
Avoid formation of respirable particles.
Avoid inhaling dust.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the ap-plication area.
Dispose of rinse water in accordance with local and national regulations.
Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.
Advice on protection against fire and explosion:
Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed.
Hygiene measures:
Avoid contact with skin, eyes and clothing. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully re-sealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.
Further information on stor-age stability:No decomposition if stored and applied as directed.
Transport information
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Marine transport (UN RTDG/IMDG)
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- -
Shipping information
- Proper shipping name and description:
- -
- Chemical name:
- -
- Labels:
- -
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Exposure controls / personal protection
Exposure controls/personal protection
Contains no substances with occupational exposure limit values.
Engineering measures
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Personal protective equipment
Eye protection:
Tightly fitting safety goggles
Hand protection
Material:
Polychloroprene - CR
Wearing time:
< 60 min
Material:
Fluorinated rubber - FKM
Wearing time:
< 60 min
Material:
Polyvinyl chloride - PVC
Wearing time:
< 60 min
Remarks:
The suitability for a specific workplace should be discussed with the producers of the protective gloves. After contamina-tion with product change the gloves immediately and dispose of them according to relevant national and local regulations
Skin and body protection:
Impervious clothing
Choose body protection according to the amount and con-centration of the dangerous substance at the work place.
Respiratory protection:
Use respiratory protective equipment when using this product at elevated temperatures (see section 8).
Filter type:
Combined inorganic and acidic gas/vapour, ammonia/amines and organic vapour type (ABEK)
Stability and reactivity
Reactivity
No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
Stable under normal conditions.
Hazardous reactions:
Under normal conditions of storage and use, hazardous reac-tions will not occur.
Conditions to avoid:
Keep away from incompatibles.
Materials to avoid:
Keep away from alkaline solutions and non-noble metals (e.g. iron, zinc, aluminum).
Hazardous decomposition products
No hazardous decomposition products are known.
Disposal considerations
Waste treatment methods
Product:
The product should not be allowed to enter drains, water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemi-cal or used container.
Send to a licensed waste management company.
Contaminated packaging:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
