Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.

Inhalation
Potential for exposure by inhalation if aerosols or mists are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.

Skin contact
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.

Eye contact
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).

Ingestion
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
When dealing with caustic substances, notify emergency physician immediately.

Notes to physician
The initial focus is only on the local action, characterized by quickly progressing deep tissue damage.
In the eye, caustic/ irritating and harmful liquids cause, depending on the intensity of exposure, various levels of irritation, destruction, and ablation of the epithelium of the conjunctiva and cornea, corneal clouding, edema and ulcerations.
Danger! Possible loss of eyesight!
Superficial irritations and damage up to ulcerations and scarring develop on the skin.
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
A specific action of the substance is unknown.
In case of substances with high water solubility, irritations up to formation of necrosis in the upper respiratory tract may result after inhalation of caustic/ irritating aerosols and mists.
The initial focus is on the local action: signs of irritation of the respiratory tract such as coughing, burning behind the sternum, tears, burning in the eyes or nose.
There is a risk of pulmonary edema!

Fire-fighting measures

Suitable extinguishing media
water spray, foam, dry powder

Extinguishing media which must not be used for safety reasons
high volume water jet

Specific hazards during fire fighting
Hazardous fumes in fires, specific to the product:
nitrogen oxides (NOx)
Carbon monoxide

Special protective equipment for fire-fighters
In case of fire use self-contained breathing apparatus if necessary.
Wear suitable protective clothing.

Further information
Water for fire fighting must not be introduced in the sewer system, subsoil, or surface waters. Assure that there are sufficient fire water retaining facilities Contaminated fire fighting water must be disposed of in conformity with the regulations of the local authorities.
Fire residues should be disposed of in accordance with the regulations.

Accidental release measures

Personal precautions
Avoid contact with skin and eyes.
Keep unauthorized persons away.
Wear personal protective equipment.

Environmental precautions
Prevent product from entering drains.
Do not allow entrance in sewage water, soil or stretches of water.

Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Fill into marked, sealable containers.

Handling and storage

Handling
Ensure that apparatus and pipelines are free from leaks. Do not ventilate into the open.
Use only permissible in closed systems. Transfer and handle product in closed systems only.
Dedicated loading/unloading stations required.
The product should only be handled by trained personnel.
Set up safety and operation procedures.
Empty, clean and dry system / system components completely before maintenance and repair work is done.
Seal container hermetically immediately after use.

Safe handling advice
If the product is thermally treated, provide for a vapour exhaust device.
Avoid contact with skin and eyes.
Wear personal protective equipment

Advice on protection against fire and explosion
Vapours may form explosive mixtures with air.
Take precautionary measures against static discharges.
Keep away from sources of ignition - No smoking.

Storage
Keep containers tightly closed in a cool, well-ventilated place.

Transport information

Land transport (ADR/RID)

UN number:
2735
Shippingopen allclose all
Class:
8
Classification code:
C7
Packaging group:
III
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2735
Shippingopen allclose all
Class:
8
Classification code:
C7
Packaging group:
III
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2735
Proper shipping name and description:
2,2,6,6-tetramethyl-4-piperidylamine
Chemical name:
Triacetondiamine
Class:
8
Packaging group:
III
EmS code:
F-A, S-B
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2735
Proper shipping name and description:
2,2,6,6-tetramethyl-4-piperidylamine
Chemical name:
Triacetondiamine
Class:
8
Packaging group:
III
Labels:
8
Remarksopen allclose all

Additional transport information

SpecialProvisionsopen allclose all
Loading instructions/Remarks
IATA_C
ERG-Code 8L
IATA_P
ERG-Code 8L
IMDG
Keep separate from acids.
Transport/further information
Keep separate from foodstuffs, luxury foods, feedstuffs

Exposure controls / personal protection

Components with workplace control parameters


Engineering measures
Refill and handle product only in closed system.
Leak detection recommended
Do not add wastewater to a biological wastewater treatment plant
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
All precautionary measures indicated have to be observed.

Exposure controls
The substance must be handled under strictly controlled conditions according to Article 18 of the REACH regulation:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.

Personal protective equipment
Respiratory protection
Use suitable respiratory protection where aerosols/vapours are generated.
use respiratory equipment with suitable filter or wear a self contained respiratory apparatus
Respirator with ABEK combination filter
Note time limit for wearing respiratory protective equipment.

Hand protection
Accidental release measures
suitable protective gloves
Glove material nitrile rubber
Material thickness 0.85 mm
Method DIN EN 374

Eye protection
close-fitting protective goggles (e.g. closed goggles)

Skin and body protection
suitable protective clothing
Use disposable clothing if appropriate.

Hygiene measures
Avoid contact with skin and eyes.
Wash off immediately in the event of contact with the skin (rinsing agent: glycol polyethylene 400), rinse off afterwards with copious amounts of water.
Remove immediately all contaminated clothing.
No eating, drinking, smoking, or snuffing tobacco at work. Wash face and/or hands before break and end of work.

Protective measures
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is important.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.

Stability and reactivity

Hazardous decomposition products
NH3

Thermal decomposition
> 200 °C

Disposal considerations

Product
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant
Uncleaned packaging
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Waste Key Number
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority