Registration Dossier

Administrative data

First-aid measures

Description of first aid measures:

In case of inhalation:
Move affected person into fresh air, keep warm and allow to rest.

In case of skin (or hair) contact:
Wash immediately with water and soap. Remove contaminated, saturated clothing immediately.

In case of eye contact:
Flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist if problems persist.

In case of ingestion:
Do not induce vomiting. Rinse mouth immediately and drink plenty of water and seek medical advice.

If there is a risk of loss of consciousness, place and transport affected person in the recovery position. No administration in cases of unconsciousness or cramps.

Most important symptoms and effects, both acute and delayed: Causes skin irritation and may cause sensitisation by skin contact.

Indication of any immediate medical attention and special treatment needed: Symptomatically treatment.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media: Dry extinguishing powder; carbon dioxide (CO2); foam.
Unsuitable extinguishing media: Full water jet.

Special hazards arising from the substance:
In case of fire may be liberated: carbon dioxide (CO2), carbon monoxide (CO), toxic pyrolysis products.

Advice for fire-fighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Keep containers cool by spaying with water if exposed to fire.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

for non-emergency personnel:
Provide adequate ventilation.
Avoid contact with skin, eyes and clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
Remove all sources of ignition, avoid heat and sparks.

for emergency responders:
In case of large amounts wear a self-contained breathing apparatus and chemical protective clothing. No further precautions.

Environmental precautions:
Do not allow to enter drains/surface water/ground-water.
Do not allow to enter into soil/subsoil.
In case of entry into waterways, soil or drains, inform the responsible authorities.
Treat the recovered material as prescribed in the section on waste disposal.

Methods and material for containment and cleaning up:
For large amount: dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material
Suitable material for taking up: universal binder.

Handling and storage

Precautions for safe handling:
Use only in well-ventilated areas.
Avoid inhalation, skin contact, eye contact.
When using do not eat, drink or smoke.
Wash hands before breaks and after work.
Remove contaminated clothing and protective equipment before entering eating areas.
Keep working clothes separately. Wash thoroughly after handling.
Only use the material in places where open light, fire and other sources of ignition can be kept away.

Conditions for safe storage, including any incompatibilities
Store in the original container under protective gas (nitrogen).
Keep container tightly closed. Keep in a cool, dry, well-ventilated place protected from direct sunlight.
Floor should be solvent-resistant, closed, sealed and not adsorbent.

Transport information

Land transport (ADR/RID)

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Methyleneundecanal)
Chemical name:
2-Methyleneundecanal
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Methyleneundecanal)
Chemical name:
2-Methyleneundecanal
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Methyleneundecanal)
Chemical name:
2-Methyleneundecanal
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Methyleneundecanal)
Chemical name:
2-Methyleneundecanal
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protective equipment:
Eye / face protection:
Suitable eye protection: Eye glasses with side protection (according to EN 166).

Skin protection:
- Hand protection:
- By long-term hand contact:
Suitable gloves type (recommended protective index 6, corresponding >480 min of permeation time according to EN 374):
Butyl caoutchouc (butyl rubber), 0.7 mm coating thickness

- By short-term hand contact
Suitable gloves type (recommended at least protective index 2, corresponding >30 min of permeation time according to EN 374):
CR (polychloroprene, chloroprene rubber) 0.5 mm coating thickness

Supplementary note:
The specifications are based on literature and information of glove manufacturer or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the determined permeation time.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

- Other: Suitable protective clothing:
For the protection against direct skin contact, body protective clothing is essential (in addition to the usual working clothes).

Respiratory protection:
Respiratory protection necessary if insufficient ventilation.
Self-contained respirator (DIN EN 133) or container device with compressed air (DIN EN 137).
Filtering device (full mask or mouthpiece) with filter A (EN 14387).

Stability and reactivity

Reactivity
No hazardous reactions known.

Chemical stability
No hazardous reaction if stored and handled as prescribed.

Possibility of hazardous reactions
No hazardous reaction if stored and handled as prescribed.

Conditions to avoid
No hazardous decomposition if stored and handled as prescribed.

Incompatible materials
No hazardous reactions known.

Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed.

Disposal considerations

Dispose of waste according to applicable legislation. Delivery to an approved waste disposal company.

List of proposed waste codes/waste designations in accordance with EWC:
Waste code product / Waste name:
07 WASTES FROM ORGANIC CHEMICAL PROCESSES
07 06 Wastes from the manufacture, formulation, supply and use (MFSU) of fats, grease, soaps, detergents, disinfectants and cosmetics.
07 06 99 Wastes not otherwise specified
07 07 Wastes from the manufacture, formulation, supply and use (MFSU) of fine chemicals and chemical products not otherwise specified.
07 07 99 Wastes not otherwise specified

Appropriate disposal / Package:
Contaminated packages must be completely emptied and can be re-used following proper cleaning.