Registration Dossier

Administrative data

First-aid measures

Remove contaminated clothing.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.

On skin contact:
Wash thoroughly with soap and water. If irritation develops, seek medical attention.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

Special hazards arising from the substance or mixture
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.

Advice for fire-fighters
Further information:
Contaminated extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Wear eye/face protection. Wear respiratory protection if ventilation is inadequate.

Environmental precautions
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up
For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.
For large amounts: Dike spillage. Pick up with suitable appliance and dispose of.

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. Remove contaminated clothing and protective equipment before entering eating areas. Hands and/or face should be washed before breaks and at the end of the shift. When using do not eat, drink or smoke.

Protection against fire and explosion:
No special precautions necessary.

Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.

Protect from temperatures below: 0 °C
The packed product is destroyed at low temperatures or by frost.
Protect from temperatures above: 50 °C
The packed product must be protected against exceeding the indicated temperature.

Transport information

Land transport (ADR/RID)

UN number:
Not classified as a dangerous good under transport regulations
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Inland waterway transport (ADN(R))

UN number:
Not classified as a dangerous good under transport regulations
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Marine transport (IMDG)

UN number:
Not classified as a dangerous good under transport regulations
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Air transport ICAO/IATA

UN number:
Not classified as a dangerous good under transport regulations
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Exposure controls / personal protection

Components with occupational exposure limits
64-19-7: acetic acid...%: TWA value 25 mg/m3 ; 10 ppm (OEL (EU)) indicative
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures
Do not inhale gases/vapours/aerosols. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:
The product is not to be labelled as corrosive for transport purposes.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
No hazardous reactions if stored and handled as prescribed/indicated.

Conditions to avoid
Temperature: > 50 °C

Incompatible materials
Substances to avoid:
strong oxidizing agents, strong alkalies

Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.