Registration Dossier
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EC number: 203-055-0 | CAS number: 102-79-4
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
General Advice
If symptoms persist, call a physician. Show this material safety data sheet to the doctor in attendance.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.
Skin Contact
Take off all contaminated clothing immediately. Soap. Consult a physician.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Consult a physician.
Ingestion
Do not induce vomiting. If conscious, drink plenty of water. Never give anything by mouth to an unconscious person. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
• Risk of serious damage to eyes
• Inhalation of vapors is irritating to the respiratory system, may cause throat pain and cough
• Shortness of breath
• nausea
Indication of immediate medical attention and special treatment needed
• Consult a physician
If symptoms persist, call a physician. Show this material safety data sheet to the doctor in attendance.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.
Skin Contact
Take off all contaminated clothing immediately. Soap. Consult a physician.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Consult a physician.
Ingestion
Do not induce vomiting. If conscious, drink plenty of water. Never give anything by mouth to an unconscious person. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
• Risk of serious damage to eyes
• Inhalation of vapors is irritating to the respiratory system, may cause throat pain and cough
• Shortness of breath
• nausea
Indication of immediate medical attention and special treatment needed
• Consult a physician
Fire-fighting measures
Suitable Extinguishing Media
• carbon dioxide (CO2)
• water spray
• dry chemical
• Alcohol-resistant foa
Extinguishing media which must not be used for safety reasons
• high volume water jet
Specific Hazards Arising from the Chemical
Specific hazards
• Vapors are heavier than air and may spread along floors
• Heating or fire can release toxic gas (Carbon monoxide, Nitrogen oxides (NOx), Ammonia)
Specific methods
• In the event of fire, cool tanks with water spray.
• Keep product and empty container away from heat and sources of ignition.
• Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Protective Equipment and Precautions for Firefighters
Wear full protective clothing and self-contained breathing apparatus.
• carbon dioxide (CO2)
• water spray
• dry chemical
• Alcohol-resistant foa
Extinguishing media which must not be used for safety reasons
• high volume water jet
Specific Hazards Arising from the Chemical
Specific hazards
• Vapors are heavier than air and may spread along floors
• Heating or fire can release toxic gas (Carbon monoxide, Nitrogen oxides (NOx), Ammonia)
Specific methods
• In the event of fire, cool tanks with water spray.
• Keep product and empty container away from heat and sources of ignition.
• Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Protective Equipment and Precautions for Firefighters
Wear full protective clothing and self-contained breathing apparatus.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
• Avoid contact with skin, eyes and clothing
• Evacuate personnel to safe areas
• Keep people away from and upwind of spill/leak
• Wear self-contained breathing apparatus and protective suit
Environmental precautions
• Should not be released into the environment
• Remove immediately adhering matter
• Prevent product from entering drains
• Do not flush into surface water or sanitary sewer system
Methods and materials for containment and cleaning up
• Use explosion-proof equipment
• Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container
• Large spills should be collected mechanically (remove by pumping) for disposal
• Avoid contact with skin, eyes and clothing
• Evacuate personnel to safe areas
• Keep people away from and upwind of spill/leak
• Wear self-contained breathing apparatus and protective suit
Environmental precautions
• Should not be released into the environment
• Remove immediately adhering matter
• Prevent product from entering drains
• Do not flush into surface water or sanitary sewer system
Methods and materials for containment and cleaning up
• Use explosion-proof equipment
• Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container
• Large spills should be collected mechanically (remove by pumping) for disposal
Handling and storage
Precautions for safe handling
• Use only in area provided with appropriate exhaust ventilation
• Use spark-proof tools and explosion-proof equipment
• Wear personal protective equipment
• Do not eat, drink or smoke when using this product
• Wash hands after handling
• Remove contaminated clothing and protective equipment before entering eating areas
• Ensure that eyewash stations and safety showers are close to the workstation location
• Avoid breathing vapors or mists
Conditions for safe storage, including any incompatibilities
• In accordance with local and national regulations
• Keep away from open flames, hot surfaces and sources of ignition
• Store in original container
• Keep container tightly closed
• Keep in a dry, cool and well-ventilated place
• Use only in area provided with appropriate exhaust ventilation
• Use spark-proof tools and explosion-proof equipment
• Wear personal protective equipment
• Do not eat, drink or smoke when using this product
• Wash hands after handling
• Remove contaminated clothing and protective equipment before entering eating areas
• Ensure that eyewash stations and safety showers are close to the workstation location
• Avoid breathing vapors or mists
Conditions for safe storage, including any incompatibilities
• In accordance with local and national regulations
• Keep away from open flames, hot surfaces and sources of ignition
• Store in original container
• Keep container tightly closed
• Keep in a dry, cool and well-ventilated place
Transport information
Land transport (ADR/RID)
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
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Inland waterway transport (ADN(R))
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
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Marine transport (IMDG)
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
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Air transport ICAO/IATA
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
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Exposure controls / personal protection
Control parameters
Exposure Guidelines
Exposure controls
Engineering Controls
• Local exhaust
Personal Protective Equipment
Eye/face Protection
• Tightly fitting safety goggles
• Face-shield
• Respirator with a full face mask
Skin Protection
• Wear suitable protective equipment
• Complete suit protecting against chemicals
Hand Protection
• Neoprene gloves
• Solvent-resistant gloves (butyl-rubber)
• The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it.
• The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Respiratory Protection
• In the case of vapor formation use a respirator with filter model K
• self-contained breathing apparatus (EN 133) (in case of higher concentration)
Environmental exposure controls
• Prevent product from entering drains
• Do not contaminate surface water
• Avoid subsoil penetration
Exposure Guidelines
Exposure controls
Engineering Controls
• Local exhaust
Personal Protective Equipment
Eye/face Protection
• Tightly fitting safety goggles
• Face-shield
• Respirator with a full face mask
Skin Protection
• Wear suitable protective equipment
• Complete suit protecting against chemicals
Hand Protection
• Neoprene gloves
• Solvent-resistant gloves (butyl-rubber)
• The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it.
• The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Respiratory Protection
• In the case of vapor formation use a respirator with filter model K
• self-contained breathing apparatus (EN 133) (in case of higher concentration)
Environmental exposure controls
• Prevent product from entering drains
• Do not contaminate surface water
• Avoid subsoil penetration
Stability and reactivity
Reactivity
Chemical Stability
• Stable under normal conditions
• Hazardous polymerisation does not occur
Possibility of hazardous reactions
None under normal processing
Conditions to Avoid
• Temperatures above 50°C
• Heat, flames and sparks
• Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors)
Incompatible materials to avoid
• Strong oxidizing agents
Hazardous Decomposition Products
• Heating or fire can release toxic gas (Nitrogen oxides (NOx), Carbon oxides)
Chemical Stability
• Stable under normal conditions
• Hazardous polymerisation does not occur
Possibility of hazardous reactions
None under normal processing
Conditions to Avoid
• Temperatures above 50°C
• Heat, flames and sparks
• Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors)
Incompatible materials to avoid
• Strong oxidizing agents
Hazardous Decomposition Products
• Heating or fire can release toxic gas (Nitrogen oxides (NOx), Carbon oxides)
Disposal considerations
Waste Disposal Method
• Should not be released into the environment
• Dispose of in accordance with local regulations
Contaminated Packaging
• Empty containers should be taken to an approved waste handling site for recycling or disposal
• Should not be released into the environment
• Dispose of in accordance with local regulations
Contaminated Packaging
• Empty containers should be taken to an approved waste handling site for recycling or disposal
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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