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Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016-05-17 to 2016-06-16
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
(EC) 440/2008
Deviations:
no
GLP compliance:
no
Other quality assurance:
other: Chilworth Technology’s Laboratories are GLP (Good Laboratory Practice) compliant and this study was carried out to the principles of GLP.
Specific details on test material used for the study:
Lot No.: 50000067900
Key result
Auto-ignition temperature:
386 °C
Atm. press.:
99.5 kPa

Hot flame autoignition temperature (AIT, °C) : 386

Including correction factor for barometric pressure (°C) : 386

Time lag to autoignition (s) : 4

Barometric pressure (kPa) : 99.5

Sample quantity (μl) : 150

Relative humidity : 53%

Details on results:

Date

Atm.
Press
(kPa)

InnerFlaskTemp(°C)

Conc.
(µl)

Clean Flask?
yes (y) / no
(n)

Ignition?
yes (y) / no
(n)

Time lag
(s)

Comments

13/06

100.3

500

100

y

y

1

Medium flame

13/06

100.3

440

100

y

y

1

Medium flame

13/06

100.3

380

100

y

n

-

-

13/06

100.3

380

150

y

n

-

-

13/06

100.3

410

100

y

y

2

Medium flame

13/06

100.3

395

100

y

n

-

-

13/06

100.3

401

100

y

y

2

Medium flame

13/06

100.3

398

100

y

y

2

Medium flame

13/06

100.3

395

150

y

y

2

Medium flame

13/06

100.1

389

150

y

n

-

-

13/06

100.1

392

150

y

n

-

-

13/06

100.1

392

200

y

n

-

-

14/06

99.6

392

300

y

y

3

Medium flame

14/06

99.6

389

300

y

n

-

-

14/06

99.6

389

400

y

y

4

Medium flame

14/06

99.6

383

400

y

n

-

-

14/06

99.6

383

500

y

n

-

-

14/06

99.6

386

400

y

n

-

-

14/06

99.6

386

500

y

n

-

-

14/06

99.6

386

600

y

n

-

-

14/06

99.6

386

300

y

n

-

-

14/06

99.6

386

200

y

n

-

-

15/06

99.5

386

150

y

y

4

Medium flame

15/06

99.5

383

150

y

n

-

-

15/06

99.5

383

200

y

n

-

-

15/06

99.5

383

300

y

n

-

-

15/06

99.5

383

400

y

n

-

-

15/06

99.5

383

100

y

n

-

-

15/06

99.5

383

50

y

n

-

-

15/06

99.5

383

500

y

n

-

-

15/06

99.5

383

600

y

n

-

-

Conclusions:
Autoignition temperature (EU-method A.15): 386 °C at atmospheric pressure
Executive summary:

The autoignition temperature for the test item was determined according to EU-method A.15.

Hot flame autoignition temperature (AIT, °C) : 386

No cool flames were observed. Ignition produced an orange flame. The time lag to autoignition was 4 seconds.

Description of key information

Autoignition temperature (EU-method A.15): 386 °C at atmospheric pressure

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
386 °C

Additional information

The autoignition temperature for the test item was determined according to EU-method A.15.

Hot flame autoignition temperature (AIT, °C) : 386

No cool flames were observed. Ignition produced an orange flame. The time lag to autoignition was 4 seconds.

According to (1), the phenomenon of self-heating applies only to solids, liquids are not classified as self-heating. Thus, no classification requirements are associated with this result.

(1) Guidance on the Application of the CLP Criteria; ECHA-15-G-05-EN, June 2015