Registration Dossier

Administrative data

First-aid measures

Skin contact: flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Eye contact: flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Ingestion: if victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. DO NOT use mouth-to-mouth respiration.

Fire-fighting measures

Suitable extinguishing media: foam, carbon dioxide (CO2), water spray.
Not suitable extinguishing media: not known.
Special protective equipment for firefighters: in the event of fire, wear a self-contained breathing apparatus and a protective suit.
Exposure hazards: under fire situation, this material may generate harmful gases such as COx, NOx and SOx.
Special methods (on small fires): if area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the area contaminated. Cool containers/tanks with spray water.

Accidental release measures

Emergency measures in case of spillage: Isolate spillage and transfer into a container.
Personal precautions: wear appropriate personal protective equipment (refer to section 8) during clean up. Avoid contact with eyes and skin. Avoid inhalation. Stay upwind.
Environmental precautions: do not flush into surface water or sanitary sewer system. If accidental spillage or washings enter drains or watercourses contact local Environment Agency.
Methods for cleaning up: evacuate area. Avoid rising of dust. Sweep up, place in a solid waste container for later disposal. Residual trace can be wiped away.

Handling and storage

HANDLING
Technical measures/Precautions: handle with appropriate personal protective equipment (refer to Section 8) under ventilation. Avoid contact with eyes and skin
Safe handling: keep away from heat and sources of ignition. Wear personal protective equipment.

STORAGE
Technical measures/Storage conditions: keep containers tightly closed in a dry and well-ventilated place at 5 °C. Store in a place accessible by authorized persons only.
Incompatible products: incompatible with strong acids and bases.
Packaging material: no materials to be specially mentioned.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Packaging group:
III
Labels:
9
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Inland waterway transport (ADN(R))

UN number:
3077
Shippingopen allclose all
Class:
9
Packaging group:
III
Labels:
9
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Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid n.o.s. (1,2,4-thiadiazol-3-ethanethioic acid, 5-amino-alpha-)
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid n.o.s. (1,2,4-thiadiazol-3-ethanethioic acid, 5-amino-alpha-)
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures: ensure adequate ventilation, especially in confined areas.

Personal protective equipment:
Respiratory protection: respirator with P2 filters.
Eye protection: safety goggles.
Hand protection: suitable protective gloves.
Skin and body protection: protective suit.
Hygiene measures: wash hands and face before breaks and immediately after handling the product. Keep away from food, drink, and animal feeding stuffs. When using, do not eat, drink, or smoke. Do not breathe dust.
Further information: remove and wash contaminated clothing and gloves, including the inside, before re-use.

Stability and reactivity

Stability: no decomposition if stored and applied as directed.
Conditions to avoid: conditions which may cause dangerous reaction are not known.
Materials to avoid: materials that may cause dangerous reactions are not known.
Hazardous decomposition products: under fire situation, this material may generate harmful gases such as COx, NOx, SOx.
Hazardous polymerization: will not occur.

Disposal considerations

Waste from residues: in accordance with local and national regulations. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not allow material to contaminate ground water system. Do not contaminate surface water.