Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
General information:
In case of accident or if you feel unwell seek medical advice (show label or SDS where possible).

After contact with the eyes:
Rinse immediately with plenty of water. Seek medical advice in case of continuous irritation.
After contact with the skin:
Wash with plenty of water or water and soap. In the event of a visible skin change or other complaints, seek medical advice (show
label or SDS where possible).
After inhalation:
Provide fresh air.
After swallowing:
Give several small portions of water to drink. Do not induce vomiting.

Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.

Indication of any immediate medical attention and special treatment needed
Further toxicology information in section 11 must be observed.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons:
water jet .

Special hazards arising from the substance or mixture
Risk of hazardous gasses or fumes in the event of fire. Exposure to combustion products may be a health hazard! Hazardous
combustion products: carbon oxides , silicon oxides , incompletely burnt hydrocarbons , toxic and very toxic fumes .

Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air. Keep unprotected persons away.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Secure the area. Wear personal protection equipment (see section Exposure controls/personal protection). Keep unprotected persons away.
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. If material is released indicate risk of slipping. Do not walk through spilled
material.

Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Close leak if possible without risk. Contain any fluid that
runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked
containers. Inform authorities if substance leaks into surface waters, sewerage or ground.

Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations. Do not flush away with water. For small
amounts: Absorb with a neutral (non-acidic / non-basic) liquid binding material such as diatomaceous earth and dispose of
according to government regulations. For large amounts: Liquids may be recovered using suction devices or pumps. If flammable,
only air driven or properly rated electrical equipment should be used. Clean any slippery coating that remains using a detergent /
soap solution or another biodegradable cleaner. Silicone fluids are slippery; spills are a safety hazard. Apply sand or other inert
granular material to improve traction.
Further information:
Exhaust vapours. Eliminate all sources of ignition. Consider explosion protection. Observe notes under section Handling and Storage.

Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment (section Exposure controls/personal protection) and on disposal (section Disposal considerations).

Handling and storage

Precautions for safe handling
Precautions for safe handling:
Ensure adequate ventilation. Must be syphoned off in situ. Spilled substance increases risk of slipping. Avoid formation of
aerosols. In case of aerosol formation special protective measures are required (exhausting by suction, respiratory protection).
Observe information in section Exposure controls/personal protection. Keep away from incompatible substances in accordance
with section Stability and reactivity.
Precautions against fire and explosion:
Product may release ethanol. Flammable vapors may accumulate and form explosive mixtures with air in containers, process
vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of
ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water.

Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
Observe local/state/federal regulations.
Advice for storage of incompatible materials:
Observe local/state/federal regulations.
Further information for storage:
Store in a dry and cool place. Protect against moisture. Store container in a well ventilated place.

Specific end use(s)
No data available.

Transport information

Land transport (ADR/RID)

Shippingopen allclose all
Remarks:
Not regulated for transport

Inland waterway transport (ADN(R))

Shippingopen allclose all
Remarks
Not regulated for transport

Marine transport (IMDG)

Remarks
Not regulated for transport

Air transport ICAO/IATA

Remarks
Not regulated for transport
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm Dust fract. Fibre/m3
64-17-5 Ethanol AGW 960,0 500,0
-
Ethanol (CAS no. 64-17-5): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German AGW.

Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Eye protection
tight fitting protective goggles .
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use. The selection of appropriate gloves not only
depends on the material, but also on other quality characteristics, and may vary depending on the manufacturer. Please observe
information from your glove supplier in terms of permeability and breakthrough time.
Skin protection
protective clothing .

Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.

Further information for system design and engineering measures
Observe information in section Handling and Storage.

Stability and reactivity

If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.

Conditions to avoid: moisture

Incompatible materials: Reacts slowly with: water . Reaction causes the formation of: ethanol . Reacts with: basic substances . Reaction causes the
formation of: heat .

Disposal considerations

Waste treatment methods

Material
Recommendation:
Material that cannot be used, reprocessed or recycled should be disposed of in accordance with Federal, State, and local
regulations at an approved facility. Depending on the regulations, waste treatment methods may include, e.g., landfill or
incineration.

Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.

Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.