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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

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Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
31 AUG - 02 SEP 2009
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Principles of method if other than guideline:
This method is based on standard DIN 51794:2003-05.
GLP compliance:
yes (incl. QA statement)
Auto-ignition temperature:
255 °C
Atm. press.:
>= 1 007 - <= 1 013 hPa

Table of results:

Stage of determination

Auto-ignition temperature [°C]

V [quantity of drops]

Corresponding time-lags [s]

Ignition temperature position for main determination (T2)

260

5

42

The lowest value from first series of tests (T4)

258

6

44

The lowest value from main determination (T5)

257

5

68

The lowest value from first repeating (T6)

261

5

30

The lowest value from second repeating (T7)

--

--

--

The lowest value from third repeating (T8)

--

--

--

The lowest experimental value of ignition temperature

257

5

68

Ignition temperature according to DIN 51794:2003-05

255

--

--

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
03 - 07 SEP 2009
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Principles of method if other than guideline:
This method is based on standard DIN 51794:2003-05.
GLP compliance:
yes (incl. QA statement)
Auto-ignition temperature:
255 °C
Atm. press.:
>= 1 000 - <= 1 014 hPa

Table of results:

Stage of determination

Auto-ignition temperature [°C]

V [quantity of drops]

Corresponding time-lags [s]

Ignition temperature position for main determination (T2)

260

5

45

The lowest value from first series of tests (T4)

258

7

70

The lowest value from main determination (T5)

259

7

75

The lowest value from first repeating (T6)

257

11

89

The lowest value from second repeating (T7)

--

--

--

The lowest value from third repeating (T8)

--

--

--

The lowest experimental value of ignition temperature

257

11

89

Ignition temperature according to DIN 51794:2003-05

255

--

--

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
13 JAN 2010
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
test procedure in accordance with national standard methods with acceptable restrictions
Qualifier:
according to guideline
Guideline:
other: ASTM E 659
GLP compliance:
no
Auto-ignition temperature:
251 °C
Atm. press.:
ca. 1 013 hPa

No data given for atmospheric pressure.

Description of key information

251 - 255 °C at 1000 - 1014 hPa

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
251 °C

Additional information

The data refer to measurements of substances of various single degrees of ethoxylation (EO = 2 and EO = 1). For a general ethoxylation degree of < 2.5 EO, a weight of evidence approach is applied.