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Environmental fate & pathways

Phototransformation in air

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Description of key information

Phototransformation in air is not relevant due to low vapour pressure (< 0.0001 Pa).

Key value for chemical safety assessment

Additional information

No experimental studies investigating the phototransformation in air of tetradecyl oleate (CAS 22393-85-7) are available. Results from AOPWIN v1.92 indicate that the substance is susceptible to indirect photodegradation in air (Müller, 2011). The estimated half-life for the reaction with OH-radicals is 4.13 h for the cis isomer and 3.82 h for the trans isomer, respectively (24 h day; OH-concentration: 0.5E+06 OH/cm³). However, this is not expected to be a relevant environmental fate process, since tetradecyl oleate is not expected to enter the atmospheric compartment based on the low estimated vapour pressure under ambient conditions (< 0.0001 Pa at 20 °C). As this study is not a standard information requirement in REACh and there is no indication from the Chemical Safety Assessment (CSA) on the need to investigate further the fate and behaviour of the substance (Annex X requirement), no further testing is considered necessary for dodecyl oleate.