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Physical & Chemical properties

Auto flammability

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Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
16 October 2009 to 08 December 2009
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP study realised according to the OECD Guideline for the Testing of Chemicals.
Qualifier:
according to
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. certificate)
Auto-ignition temperature:
316 °C
Atm. press.:
> 1 008 - < 1 012 mBar
Remarks on result:
other:

Table1: results

 Test temperature (°C)   Test volume (μl)   Time (s)   Observation 
 400   70   2   Yellow flame 
 300   70   >300   White smoke, no ignition 
 300   1000   >300   White smoke, no ignition 
 350   70   5   Yellow flame 
 330   70   13   Yellow flame 
 320   70   >300   White smoke, no ignition 
 320   1000   >300   White smoke, no ignition 
 326   70   >300   White smoke, no ignition 
 326   1000   >300   White smoke, no ignition 
 328   70   >300   White smoke, no ignition 
 328   1000   >300   White smoke, no ignition 
 328   100   10   Yellow flame 
 324   100   13   Yellow flame 
 320   100   16   Yellow flame 
 316   100   18   Yellow flame 
 310   100   >300   White smoke, no ignition 
 312   100   >300   White smoke, no ignition 
 314   100   >300   White smoke, no ignition 
 314   200   >300   White smoke, no ignition 
 314   500   >300   White smoke, no ignition 
 314   70   >300   White smoke, no ignition 
 314   1000   >300   White smoke, no ignition 
 314   100   >300   White smoke, no ignition 
 314   100   >300   White smoke, no ignition 
 314   100   >300   White smoke, no ignition 
 314   100   >300   White smoke, no ignition 
 314   100   >300   White smoke, no ignition 
Conclusions:
1,3-Bis(aminomethyl)cyclohexane was determined to have an auto-ignition temperature of 316°C.
Executive summary:

A package of physico-chemical testing including an auto-ignition temperature determination was conducted on the test substance 1,3 -Bis(aminomethyl)cyclohexane. The test package was conducted in compliance with GLP, and the auto-ignition temperature determination was performed according to EU Test Method A15.

1,3-Bis(aminomethyl)cyclohexane was determined to have an auto-ignition temperature of 316°C.

Endpoint:
auto-flammability
Type of information:
other: MSDS
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
other: Source of data is publicly available MSDS sheet
Auto-ignition temperature:
335 °C
Conclusions:
According to publicly available MSDS, the auto flammability point is 335°C.
Executive summary:

A value for the autoignition temperature of the test substance 1,3 -Bis(aminomethyl)cyclohexane (1,3 -BAC) was taken from a publically available MSDS, prepared by Mitsubishi Gas Chemical Company, Inc.

Description of key information

1,3-Bis(aminomethyl)cyclohexane was determined to have an auto-ignition temperature of 316°C.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
316 °C

Additional information

A package of physico-chemical testing including an auto-ignition temperature determination was conducted on the test substance 1,3 -Bis(aminomethyl)cyclohexane. The test package was conducted in compliance with GLP, and the auto-ignition temperature determination was performed according to EEC Method A15.

1,3-Bis(aminomethyl)cyclohexane was determined to have an auto-ignition temperature of 316°C.

The auto-ignition temperature was quoted on a publically-available MSDS as 335°C. As the methodology used to record this value could not be verified, the reliability of the result could not be verified, and so the experimentally derived result (above) was reported.