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EC number: 466-480-2 | CAS number: -
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Repeated dose toxicity: oral
Administrative data
- Endpoint:
- short-term repeated dose toxicity: oral
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 10 July 2006 to 20 November 2006
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 006
- Report date:
- 2006
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 407 (Repeated Dose 28-Day Oral Toxicity Study in Rodents)
- Deviations:
- not specified
- Qualifier:
- according to guideline
- Guideline:
- EU Method B.7 (Repeated Dose (28 Days) Toxicity (Oral))
- Qualifier:
- according to guideline
- Guideline:
- other: Japanese Guidelines for Screening, Toxicity Testing of Chemicals: Testing Methods for new Substances, enacted July 13, 1974, amended December 5, 1986
- GLP compliance:
- yes
- Limit test:
- no
Test material
- Test material form:
- solid: particulate/powder
- Remarks:
- migrated information: powder
- Details on test material:
- - Name of test material (as cited in study report): FAT 40826/A
- Lot/batch No.: TZ 5604 BAP 01/06
- Expiration date: 1 February 2011
- Purity: approx. 48%
- Storage conditions: At room temperature (range of 20 ± 5 °C), in an exsiccator away from direct sunlight.
- Stability: Stable under storage conditions
Constituent 1
- Specific details on test material used for the study:
- Identity: FAT 40826/A
Batch no.: TZ 5604 BOP 01/06
Expiration date: February 01, 2011
Purity: Content of organic part (Na-salt): approx. 78 %; Oligomers: 13 %; Main component: approx. 48 %
Solubility in water: Approx. >50 g/L at room temperature
Stability in water: Max. 7 days at room temperature
pH: 7.6 (1 g/L)
Aggregate state/physical form at room temperature: Solid (orange powder)
Storage conditions: At room temperature at about 20 °C, away from direct sunlight
Specific instructions: Store in desiccator
Test animals
- Species:
- rat
- Strain:
- Wistar
- Details on species / strain selection:
- Rationale Recognized by the international guidelines as the recommended test system.
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- TEST ANIMALS
- Source: RCC Ltd, Laboratory Animal Services, CH-4414 Füllinsdorf / Switzerland
- Age at delivery: 6 weeks
- Weight at acclimatization: Males: 135.4-159.3 grams (mean 148.1 grams), Females: 113.3- 131.1 grams (mean 121.3 grams)
- Housing: In groups of five in Makrolon type-4 cages with wire mesh tops and standardized softwood bedding ('Lignocel' Schill AG, CH-4132 Muttenz/Switzerland).
- Diet: Pelleted standard Provimi Kliba 3433 (batch nos. 23/06 and 36/06) rat maintenance diet (Provimi Kliba AG, CH-4303 Kaiseraugst/ Switzerland), ad libitum.
- Water: Community tap-water from Itingen was available ad libitum in water bottles.
- Acclimation period: Under test conditions after health examination. Only animals without any visible signs of illness were used for the study.
ENVIRONMENTAL CONDITIONS
- Temperature (°C): 22±3
- Humidity (%): 30-70
- Air changes (per hr): 10-15
- Photoperiod (hrs dark / hrs light): 12/12
Administration / exposure
- Route of administration:
- oral: gavage
- Details on route of administration:
- Rationale: Administration by gavage is a common and accepted route of exposure for studies of this type.
- Vehicle:
- water
- Remarks:
- bidistilled water
- Details on oral exposure:
- PREPARATION OF DOSING SOLUTIONS:
The dose formulations were prepared weekly. FAT 40826/A was weighed into a glass beaker on a tared Mettler balance and the vehicle added. The mixtures were prepared weekly using a magnetic stirrer and stored at room temperature (20±5 °C) in glass beakers. Homogeneity of the test item in the vehicle was maintained during the daily administration period using a magnetic stirrer.
Dose volume: 10 mL/kg body weight - Analytical verification of doses or concentrations:
- yes
- Details on analytical verification of doses or concentrations:
- Concentration, homogeneity and stability (after 2 hours and 7 days) of the dose formulations were determined in samples taken after experimental start. Concentration and homogeneity of the dose formulations were determined in samples taken during week 3 of the treatment.
- Duration of treatment / exposure:
- 28 days
- Frequency of treatment:
- daily
Doses / concentrationsopen allclose all
- Dose / conc.:
- 0 mg/kg bw/day (actual dose received)
- Remarks:
- Control
- Dose / conc.:
- 50 mg/kg bw/day (actual dose received)
- Remarks:
- Low dose
- Dose / conc.:
- 200 mg/kg bw/day (actual dose received)
- Remarks:
- Middle dose
- Dose / conc.:
- 1 000 mg/kg bw/day (actual dose received)
- Remarks:
- High dose
- No. of animals per sex per dose:
- 30 males and 30 females;
Groups 0 mg/kg/day and 1000 mg/kg/day: 10 males; 10 females
Groups 50 mg/kg/day and 200 mg/kg/day: 5 males; 5 females - Control animals:
- yes, concurrent vehicle
- Details on study design:
- - In this subacute toxicity study, FAT 40826/A was administered daily by oral gavage to SPF-bred Wistar rats of both sexes at dose levels of 50, 200 and 1000 mg/kg body weight/day for a period of 28 days. A control group was treated similarly with the vehicle, bidistilled water, only. The groups comprised 5 animals per sex that were sacrificed after 28 days of treatment. Additional 5 rats per sex and group were used at 0 and 1000 mg/kg. These animals were treated for 28 days and then allowed a 14 day treatment-free recovery period after which they were sacrificed.
- Rationale for dose level selection: Based upon the results of a non-GLP 5-day dose range-finding study (RCC Study Number A73697) in which FAT 40826/A was administered by gavage to 2 rats per group and sex.
Examinations
- Observations and examinations performed and frequency:
- - Mortality/viability: Observations for mortality/viability were recorded twice daily.
- Cage side observations: The animals were observed for clinical signs once before commencement of administration; twice daily on days 1-3; as well as once daily on days 4-28 and once daily during days 29-42 (recovery).
- Clinical observations: The animals were observed in their home cages, outside their home cages in a standard arena and in the hand. These observations were performed in random sequence once before commencement of administration and once weekly (weeks 1-3) thereafter.
- Food consumption: The food consumption was recorded once during the pretest period and weekly thereafter.
- Body weight: Body weights were recorded weekly during the pretest, treatment and recovery and before necropsy.
- Functional observational battery: During week 4, relevant parameters from a modified Irwin screen test were evaluated in all animals. Grip strength: Forelimb and hind limb grip strength measurements were performed using a push-pull strain gauge (Mecmesin, AFG 25N). The animals were placed with the forepaws inside a triangular grasping ring and with the hind paws outside a triangular grasping ring. Using one hand, the animals were held towards the base of the tail and steadily pulled away or towards the ring until the grip was broken. Each measurement was repeated three times, the means were calculated and recorded. Locomotor activity: Locomotor (decreased or increased) activity was measured quantitatively with AMS Föhr Medical Instruments GmbH (FMI) and DeMeTec GmbH Activity monitor System. Animals were monitored during the fourth treatment week for a 60-minute period and the total activity of this time period was recorded. Low beams count was reported in 10-minute intervals as well as the total activity of the measuring period.
- Clinical laboratory investigations: Blood samples were drawn from the retro-orbital plexus from all animals under light isoflurane anesthesia. The animals were fasted in metabolism cages for approximately 18 hours before blood sampling but allowed access to water ad libitum. The samples were collected early in the working day to reduce biological variation caused by circadian rhythms. Urine was collected during the 18 hours fasting period into a specimen vial, using a metabolism cage. The following hematology parameters were determined: Erythrocyte count, Hemoglobin, Hematocrit, Mean corpuscular volume, Red cell volume distribution width, Mean corpuscular hemoglobin, Mean corpuscular hemoglobin concentration, Hemoglobin concentration distribution width, Platelet count, Reticulocyte count, Reticulocyte maturity index, Leukocyte count, Differential leukocyte count, Heinz bodies, Methemoglobin, Thromboplastin time, Activated partial thromboplastin time. The following clinical biochemistry parameters were determined: Glucose, Urea, Creatinine, Bilirubin, Cholesterol, Triglycerides, Phospholipids, Aspartate aminotransferase, Alanine aminotransferase, Lactate dehydrogenase, Glutamate dehydrogenase, Creatine kinase, Alkaline phosphatase, Gamma-glutamyl-transferase, Sodium, Potassium, Chloride, Calcium, Phosphorus inorganic, Protein, Albumin, Globulin, Albumin/Globulin ratio. The following urinalysis parameters were determined: Volume (18 hours), Specific gravity (relative density), Color, Appearance, pH, Nitrite, Protein, Glucose, Ketones, Urobilinogen, Bilirubin, Erythrocytes, Leukocytes. - Sacrifice and pathology:
- - All animals were weighed and necropsied. Descriptions of all macroscopic abnormalities were recorded.
- All animals surviving to scheduled necropsy were anesthetized by intraperitoneal injection of sodium pentobarbitone and killed by exsanguination.
Samples of the following tissues and organs were collected from all animals at necropsy and fixed in neutral phosphate buffered 4 % formaldehyde solution (unless otherwise indicated): Adrenal glands, Aorta, Bone (sternum, femur including joint), Bone marrow (femur), Brain (4 levels), Cecum, Colon, Duodenum, Epididymites (fixed in Bouin's solution), Esophagus, Eyes with optic nerve (fixed in Davidson's solution), Harderian gland (fixed in Davidson's solution), Heart, Ileum with Peyer's patches, Jejunum with Peyer's patches, Kidneys, Larynx, Lacrimal gland (exorbital), Liver, Lungs (infused with formalin at necropsy), Lymph nodes (mesenteric, mandibular), Mammary gland area, Nasal cavity, Ovaries, Pancreas, Pituitary gland, Prostate gland (incl. coagulating gland), Rectum, Salivary glands (mandibular, sublingual), Sciatic nerve, Seminal vesicles, Skeletal muscle, Skin, Spinal cord (cervical, mid-thoracic, lumbar), Spleen, Stomach, Testes (fixed in Bouin's solution), Thymus, Thyroid (incl. parathyroid gland), Tongue, Trachea, Urinary bladder (infused with formalin at necropsy), Uterus, Vagina, Gross lesions.
-The following organ weights were recorded on the scheduled dates of necropsy: Brain, Heart, Liver, Thymus, Kidneys, Adrenals, Spleen, Testes, Epididymites, Ovaries. The organ to terminal body weight ratios as well as organ to brain weight ratios were determined. The determination of the terminal body weight was performed immediately prior to necropsy.
- Slides of organs and tissues that were collected at scheduled sacrifice from the animals of control and high-dose groups were examined by a pathologist. Due to findings in the high dose group, forestomach from the animals of the low and middle dose groups were examined to establish a no-effect level. - Statistics:
- The following statistical methods were used to analyze the grip strength, locomotor activity, body weight, clinical laboratory investigations, organ weights and ratios and macroscopic findings as well as:
• The Dunnett-test (many to one t-test) based on a pooled variance estimate were applied if the variables could be assumed to follow a normal distribution for the comparison of the treated groups and the control groups for each sex.
• The Steel-test (many-one rank test) was applied instead of the Dunnetttest when the data could not be assumed to follow a normal distribution.
• Fisher's exact-test was applied to the macroscopic findings.
• Student's t-test was applied to grip strength and locomotor activity data.
Results and discussion
Results of examinations
- Clinical signs:
- no effects observed
- Description (incidence and severity):
- However, alopecia on the left shoulder was found in one male (no. 18) treated with 200 mg/kg/day during the last three days of treatment. One female (no. 47) treated with 200 mg/kg/day transiently had crusts around the left eye during days 14-17 of treatment.
- Mortality:
- no mortality observed
- Description (incidence):
- However, One female of the control group (No. 35) died in anesthesia after blood sampling on the scheduled day of necropsy.
- Body weight and weight changes:
- effects observed, non-treatment-related
- Description (incidence and severity):
- In test item treated males, the mean body weight was slightly higher than in controls during treatment and recovery. The difference was statistically significant in weeks 2 and 3 in males treated with 1000 mg/kg/day and in week 4 in males treated with 200 mg/kg/day. Mean body weight gain tended to be increased during weeks 1 to 3 in all test item treated males without statistical significance. Insofar as there was no dose relation, this finding is considered not to be test item-related. In test item treated females, mean body weight and body weight gain were comparable to that of controls.
- Food consumption and compound intake (if feeding study):
- no effects observed
- Food efficiency:
- no effects observed
- Haematological findings:
- effects observed, non-treatment-related
- Description (incidence and severity):
- In males treated with 1000 mg/kg/day, the following statistically significant changes were found after 4 weeks of treatment: Mean cell haemoglobin and mean cell haemoglobin concentration were decreased with dose relationship. Absolute and relative number of reticulocytes and absolute number of eosinophils was increased. Absolute number of large unstained cells was increased and the prothrombin time was elevated. In females treated with 1000 mg/kg/day, the following statistically significant changes were found after 4 weeks of treatment: Mean cell haemoglobin concentration was decreased. The absolute number of large unstained cells was increased and the prothrombin time was elevated. White blood cell count, the number of lymphocytes, and the number of basophils were increased. Methemoglobin was slightly decreased. After 2 weeks of recovery, increased red cell distribution width and partial thromboplastin time were noted in males treated with 1000 mg/kg/day only. However, these findings were within the range of normal biological variation in rats of this strain and age and are considered to be of no toxicological relevance.
- Clinical biochemistry findings:
- no effects observed
- Urinalysis findings:
- no effects observed
- Description (incidence and severity):
- The few findings in urinalysis after 4 weeks only were minor, inconsistent across sexes and either without dose relation or within the range of normal biological variation for rats of this strain and age.
- Behaviour (functional findings):
- effects observed, non-treatment-related
- Description (incidence and severity):
- Grip Strength
No test item-related differences were noted in the mean grip strength when compared with the controls. A statistically significant decrease was noted in forelimb grip strength of females treated with 1000 mg/kg/day. This observation was neither dose related nor consistent across sexes, and is therefore considered to be incidental.
Locomotor Activity
No test item-related differences were noted in the mean locomotor activity when compared with the controls. A statistically significant increase in locomotor activity was seen from 0-10 min. in females treated with 200 or 1000 mg/kg/day (p <0.01). As this observation was not consistent across sexes, it is considered to be incidental. - Organ weight findings including organ / body weight ratios:
- effects observed, non-treatment-related
- Description (incidence and severity):
- After 4 Weeks
In females treated with 1000 mg/kg/day, a decrease in adrenal weight was noted, and was statistically significant in absolute weight and adrenal to brain weight ratio. This is considered to be a stress response. - Gross pathological findings:
- effects observed, non-treatment-related
- Description (incidence and severity):
- After 4 weeks of treatment, one male treated with 50 mg/kg/day had enlarged bronchial lymph nodes. Discoloration of the ovaries was found in one female of the control group and watery cysts in the ovaries were found in one female treated with 1000 mg/kg/day. After the recovery period, one male and one female of the control group showed renal pelvic dilation. Foci in the thymus were found in one male of the control group and one female treated with 1000 mg/kg/day. One male treated with 1000 mg/kg/day showed discoloration of the pancreas and one female had foci in the stomach. These findings are within the range of normal findings in rats of this strain and age and are considered to be incidental.
- Histopathological findings: neoplastic:
- effects observed, treatment-related
- Description (incidence and severity):
- After 4 weeks of treatment, minimal to slight reversible focal spongiosis of the stratified squamous epithelium in the forestomach at the limiting ridge between forestomach and glandular stomach was found in all animals treated with 1000 mg/kg/day and in none of the controls. Additionally, minimal diffuse hyperkeratosis of the forestomach epithelium was found in all animals treated with 1000 mg/kg/day, in 3 of 5 males and females each treated with 50 mg/kg/day, in 3 of 5 males and 4 of 5 females treated with 200 mg/kg/day, and in 4 of 5 males and 3 of 5 females of the control group. Focal spongiosis of the stratified squamous epithelium in the forestomach is regarded as test item-related whereas minimal diffuse hyperkeratosis is regarded as treatment-related minimal local irritation. After recovery, spongiosis was not found and the incidence of hyperkeratosis in controls and test item treated animals was comparable.
All other microscopic findings noted were considered to be incidental as their morphology, severity, and incidence did not distinguish treated rats from control rats.
Effect levels
open allclose all
- Dose descriptor:
- NOAEL
- Effect level:
- 1 000 mg/kg bw/day (actual dose received)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- other: Study findings
- Dose descriptor:
- NOEL
- Effect level:
- 200 mg/kg bw/day (actual dose received)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- other: Study findings
Target system / organ toxicity
- Critical effects observed:
- not specified
Applicant's summary and conclusion
- Conclusions:
- The No Observed Adverse Effect Level (NOAEL) of FAT 40826/A in 28-day repeated dose toxicity study in Wistar rats was determined to be 1000 mg/kg bw/day.
- Executive summary:
In ta GLP-compliant subacute toxicity study, FAT 40826/A was administered daily by oral gavage to Wistar rats of both sexes at dose levels of 50, 200 and 1000 mg/kg body weight/day for a period of 28 days. A control group was treated similarly with the vehicle, bi-distilled water, only. The study was carried out according to OECD 407 and EU method B.7. The groups comprised 5 animals per sex, which were sacrificed after 28 days of treatment. Additional 5 rats per sex and group were used at 0 and 1000 mg/kg. These animals were treated for 28 days and then allowed a 14-day treatment-free recovery period after which they were sacrificed. Clinical signs, food consumption and body weights were recorded periodically during acclimatization, the treatment and recovery periods. Functional observational battery, locomotor activity and grip strength were performed during week 4. At the end of the dosing and the treatment-free recovery period, blood samples were withdrawn for hematology and plasma chemistry analyses. Urine samples were collected for urinalyses. All animals were killed, necropsied and examined post mortem. Histological examinations were performed on organs and tissues from all control and high dose animals. From the animals of the low and middle dose groups, forestomach were examined to establish a no-effect level. Oral administration of the test substance for 28 days did not resulted in mortality, clinical signs, effects on grip strength or locomotor activity, effects on food consumption, and effects on body, organ weight, clinical pathology and gross pathology. There was minimal to slight focal spongiosis of the stratified squamous epithelium in the forestomach in all animals treated with 1000 mg/kg/day is regarded as test item-related but was reversible after recovery and therefore is considered not to be adverse. Minimal diffuse reversible hyperkeratosis of the forestomach epithelium present in all animals treated with 1000 mg/kg/day and in some males and females treated with 200 or 50 mg/kg/day or of the control group was regarded as treatment-related minimal local irritation. Based on the study findings 200 mg/kg bw/day of FAT 40826/A was established as the no-observed-effect-level (NOEL) and 1000 mg/kg bw/day of FAT 40826/A as the no-observed-adverse-effect-level (NOAEL).
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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