Registration Dossier
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EC number: 231-143-9 | CAS number: 7440-33-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Ecotoxicological Summary
Administrative data
Hazard for aquatic organisms
Freshwater
- Hazard assessment conclusion:
- PNEC aqua (freshwater)
- PNEC value:
- 0.338 mg/L
- Assessment factor:
- 10
- Extrapolation method:
- assessment factor
- PNEC freshwater (intermittent releases):
- 0.31 mg/L
Marine water
- Hazard assessment conclusion:
- PNEC aqua (marine water)
- PNEC value:
- 0.034 mg/L
- Assessment factor:
- 100
- Extrapolation method:
- assessment factor
STP
- Hazard assessment conclusion:
- PNEC STP
- PNEC value:
- 5.86 mg/L
- Assessment factor:
- 100
- Extrapolation method:
- assessment factor
Sediment (freshwater)
- Hazard assessment conclusion:
- PNEC sediment (freshwater)
- PNEC value:
- 960 mg/kg sediment dw
- Assessment factor:
- 10
- Extrapolation method:
- equilibrium partitioning method
Sediment (marine water)
- Hazard assessment conclusion:
- PNEC sediment (marine water)
- PNEC value:
- 96 mg/kg sediment dw
- Assessment factor:
- 10
- Extrapolation method:
- equilibrium partitioning method
Hazard for air
Air
- Hazard assessment conclusion:
- no hazard identified
Hazard for terrestrial organisms
Soil
- Hazard assessment conclusion:
- PNEC soil
- PNEC value:
- 2.17 mg/kg soil dw
- Assessment factor:
- 10
- Extrapolation method:
- assessment factor
Hazard for predators
Secondary poisoning
- Hazard assessment conclusion:
- PNEC oral
- PNEC value:
- 0.011 g/kg food
- Assessment factor:
- 90
Additional information
No definitive results were available from tests performed with tungsten metal. Therefore, the most reliable studies identified for sodium tungstate were used in for read-across in the PNEC derivations. This approach is considered to be appropriate since sodium tungstate has been shown to undergo more dissolution in water solutions mimicking natural water conditions than tungsten metal. Hence, sodium tungstate is likely to be more bioavailable than tungsten metal and adequately protective for estimating potential toxicity. Furthermore, neither tungsten metal or sodium tungstate are classified for aquatic toxicity and their PBT profile is the same. For further details regarding the appropriateness of read-across, see the attached read-across document.
Conclusion on classification
Aquatic toxicity classification of inorganic metals and metal compounds is conducted by comparing transformation/dissolution (T/D) data for the substance, generated using the standard protocol (UN GHS, 2007, Annex 10) [see Table 3 in Section 1.3 for results] with toxicity data for the most soluble metal substance as described in the CLP technical guidance (section IV. 5 Application of classification criteria to metals and metal compounds) (EU, 2008). In the case of tungsten metal, T/D data for tungsten metal is compared to the aquatic toxicity reference values derived from read-across to sodium tungstate. The T/D data is ideally tested at the pH at which the highest dissolution is expected, within the range defined by the test protocol (pH 5.5-8.5). Since inorganic tungsten substances have been demonstrated to have a higher T/D rate at pH 8.5 than pH 6, the data used for aquatic toxicity classification of tungsten metal was derived at pH 8.5 (7- and 28-day T/D testing) (CANMET-MMSL, 2010). These T/D values were compared to the corresponding acute (31000 ug W/L, based on the ErC50) and chronic (3380 ug W/L, based on the ErC10) aquatic toxicity reference values derived from sodium tungstate testing of algae, as the most sensitive standard aquatic species. The results of this comparison demonstrate that tungsten metal does not classify for aquatic toxicity.
Table 53. Classification of tungsten metal using T/D data comparison to toxicity data according to CLP
Test type/ duration | T/D loading amount as W (mg/L) | T/D results (μg W/L) | Toxicity reference value (μg W/L) | Comparison of T/D and toxicity values (μg W/L) | Aquatic toxicity classification result |
Acute full test/ 7 days | 1 | 52 | Acute= 31000 | 52<31000 | No Acute 1 classification |
Acute full test/ 7 days | 10 | 988 | Acute= 31000 | 988<31000 | No Acute 2 classification |
Acute full test/ 7 days | 100 | 16509 | Acute= 31000 | 16509<31000 | No Acute 3 classification |
Chronic full test/ 28 days | 1 | 188 | Chronic=3380 | 188<3380 | No Chronic 4 classification |
CLASSIFICATION CONCLUSION | No aquatic toxicity classification |
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