Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 233-042-5 | CAS number: 10025-78-2
Dissociation constant
Administrative data
Link to relevant study record(s)
- Endpoint:
- dissociation constant
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- the study does not need to be conducted because the substance is hydrolytically unstable (half-life less than 12 hours)
Reference
Description of key information
Dissociation constant [trichlorosilane]: Not relevant due to very rapid hydrolysis in contact with water
Dissociation constant [silicic acid]: pKa1 = 9.9
Key value for chemical safety assessment
Additional information
The requirement to test the substance for dissociation constant is waived because in contact with water the substance hydrolyses very rapidly to form silanetriol/monosilicic acid and hydrochloric acid.
Monosilicic acid was reported to have dissociation constant values of pKa1 = 9.9, pKa2 = 11.8, pKa3 and pKa4 = 12 at 30°C in a secondary data source which has been subject to peer review and in which the original sources are traceable. Monosilicic acid is, therefore, an extremely weak acid. In neutral solution, the undissociated form will dominate.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
