Registration Dossier
Registration Dossier
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EC number: 200-579-1 | CAS number: 64-18-6
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, alcohol-resistant foam, carbon dioxide
5.2. Special hazards arising from the substance or mixture
carbon monoxide
The substances/groups of substances mentioned can be released in case of fire.
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not empty into drains.
6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. acid binder).
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Handling and storage
7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Sealed containers should be protected against heat as this results in pressure build-up.
Protection against fire and explosion:
Sources of ignition should be kept well clear.
Temperature class: T1 (Autoignition temperature > 450 °C).
7.2. Conditions for safe storage, including any incompatibilities
Segregate from alkalies and alkalizing substances.
Suitable materials for containers: Stainless steel 1.4571, Stainless steel 1.4404, Stainless steel 1.4541, Stainless steel 1.4306 (V2A), Stainless steel 1.4307, Stainless steel 1.4311, High density polyethylene (HDPE), Low density polyethylene (LDPE), glass
Further information on storage conditions: Danger of bursting when sealed gastight.
Storage stability:
Storage temperature: < 30 °C
Storage duration: <= 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
7.3. Specific end use(s)
See exposure scenario(s) in the attachment to this safety data sheet.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
64-18-6: formic acid...%
OEL 9,5 mg/m3 ; 5 ppm (TRGS 900 (DE))
Ceiling limit value/factor: 2
If the occupational exposure limit value (AGW) and the biological limit value (BGW) are complied with, there should be no risk of damage for the unborn child (see TRGS 900, Number 2.7)
TWA value 9 mg/m3 ; 5 ppm (OEL (EU))
indicative
Short Term Exposure Classification: (TRGS 900 (DE))
Category I: Substances for which the localized effect has an assigned exposure limit or for substances with a sensitizing effect in respiratory passages
PNEC
freshwater: 2 mg/l
marine water: 0,2 mg/l
intermittent release: 1 mg/l
sediment (freshwater): 13,4 mg/kg
sediment (marine water): 1,34 mg/kg
soil: 1,5 mg/kg
STP: 7,2 mg/l
DNEL
worker:
Long-term exposure - systemic and local effects, Inhalation: 9,5 mg/m3
consumer:
Short-term exposure - systemic and local effects, Inhalation: 9,5 mg/m3
consumer:
Long-term exposure - systemic and local effects, Inhalation: 3 mg/m3
worker:
Short-term exposure - systemic and local effects, Inhalation: 19 mg/m3
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Gas filter for acid inorganic gases/vapours such as SO2, HCl (e.g. EN 14387 Type E). Gas filter for gases/vapours of inorganic compounds (e.g. EN 14387 Type B) Combination filter for gases/vapours of organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK). Suitable respiratory protection for higher concentrations or long-term effect: Self-contained breathing apparatus.
Consider the risk management measures as outlined in the exposure scenario.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
chloroprene rubber (CR) - 0.5 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Avoid contact with the skin, eyes and clothing. Avoid inhalation of vapour. Avoid contact with skin and eyes. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Hands and/or face should be washed before breaks and at the end of the shift. When using, do not eat, drink or smoke.
Stability and reactivity
10.1. Reactivity
Corrosion to metals:
No corrosive effect on metal.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
10.2. Chemical stability
Slow decomposition possible.
10.3. Possibility of hazardous reactions
Exothermic reaction. Reacts with alkalies. Reacts with amines. The formation of gaseous decomposition products builds up pressure in tightly closed containers.
10.4. Conditions to avoid
Temperature: > 30 °C
10.5. Incompatible materials
Substances to avoid:
bases, non-coated metals, base metals
10.6. Hazardous decomposition products
Hazardous decomposition products:
carbon monoxide
Disposal considerations
13.1. Waste treatment methods
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Incinerate in suitable incineration plant, observing local authority regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
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