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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

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Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
data from handbook or collection of data
Principles of method if other than guideline:
no data on method
GLP compliance:
not specified
Type of method:
closed cup
Flash point:
38 °C
Atm. press.:
1 013 hPa
Remarks on result:
other:
Remarks:
Corresponding pressure is not specified, probably at 1013 hPa

Corresponding pressure is not specified.

Executive summary:

The flash point of hydrazine accounts for 38 °C (NIOSH, 1995).

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study without detailed documentation
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
GLP compliance:
no
Type of method:
closed cup
Remarks on result:
not determinable, other reason:
Remarks:
From up 30 °C the ignition flame became greater when dipping into the gas room of the cup. At 75 °C the ignition flame stripped from the ignition burner. The flashpoint cannot be determined exactly.

From up 30 °C the ignition flame became greater when dipping into the gas room of the cup. At 75 °C the ignition flame stripped from the ignition burner. The flashpoint can’t determinded exactly.

Executive summary:

For hydrazine hydrate, no exact flash point could be determined (Currenta, 2010).

Description of key information

The flash point of hydrazine accounts for 38 °C (NIOSH, 1995). 
No exact flash point could be determined for hydrazine hydrate (Currenta, 2010).

Key value for chemical safety assessment

Flash point at 101 325 Pa:
38 °C

Additional information

Based on the available information, hydrazine has to be classified as:

- flammable, R10 (Directive 67/548/EEC)

- flammable liquid and vapour, flam. liquid cat. 3 (Regulation EC 1208/2008)

Testing hydrazine hydrate in a closed cup, from up 30 °C the ignition flame became greater when dipping into the gas room of the cup. At 75 °C the ignition flame stripped from the ignition burner. The flashpoint could not be determinded exactly.