6-phenyl-1,3,5-triazine-2,4-diyldiamine

Guidance on Safe Use

First-aid measures

· General information:

Immediately remove any clothing contaminated by the product.

Symptoms of poisoning may occur after several hours. Medical observation for at least 48 hours after the

accident is recommended.

· After inhalation:

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor.

In case of unconsciousness bring patient into stable side position for transport.

· After skin contact:

Wash with soap and water.

If skin irritation continues, consult a doctor.

· After eye contact:

Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.

· After swallowing:

Rinse out mouth and then drink plenty of water.

If swallowed, seek medical advice immediately and show this container or label.

Fire-fighting measures

Suitable extinguishing agents

Carbon dioxide (CO₂), extinguishing powder or water spray/fog. Fight larger fires with water spray/fog or

alcohol-resistant foam.

· For safety reasons unsuitable extinguishing agents Water with a full water jet.

· Special hazards caused by the material, its products of combustion or flue gases:

Nitrogen oxides (NOx)

Carbon monoxide (CO) and Carbon dioxide (CO₂)

· Protective equipment: Wear self-contained breathing apparatus.

· Additional information

Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

Accidental release measures

Person-related safety precautions:

Ensure adequate ventilation.

Avoid causing dust.

Avoid breathing dust.

Avoid contact with skin and eyes.

· Measures for environmental protection:

Do not allow to enter drainage system, surface or ground water.

Inform respective authorities in case product reaches water or sewage system.

· Measures for cleaning/collecting:

Ensure adequate ventilation.

Collect mechanically.

Dispose of the material collected according to regulations.

Handling and storage

· Handling

· Information for safe handling:

Ensure good ventilation/exhaustion at the workplace.

Prevent formation of dust.

Any deposit of dust which cannot be avoided must be removed regularly.

Do not breathe dust.

Avoid prolonged or repeated skin contact.

Avoid contact with eyes.

· Information about protection against explosions and fires:

The product forms flammable fumes when heated.

Keep ignition sources away - Do not smoke.

Protect against electrostatic charges.

· Storage

· Requirements to be met by storerooms and containers:

Observe all local and national regulations for storage of water polluting products.

· Information about storage in one common storage facility: Store away from oxidizing agents.

· Further information about storage conditions:

Store in cool, dry conditions in well sealed containers.

Store container in a well ventilated position.

Recommended storage temperature: 15 - 25°C

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

not applicable, no dangerous good for transport

Shipping

Labels:

not applicable, no dangerous good for transport

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

not applicable, no dangerous good for transport

Shipping

Labels:

not applicable, no dangerous good for transport

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

not applicable, no dangerous good for transport

Shipping information

Proper shipping name and description:

not applicable, no dangerous good for transport

Chemical name:

not applicable, no dangerous good for transport

Labels:

not applicable, no dangerous good for transport

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

not applicable, no dangerous good for transport

Shipping information

Proper shipping name and description:

not applicable, no dangerous good for transport

Chemical name:

not applicable, no dangerous good for transport

Labels:

not applicable, no dangerous good for transport

Remarks

SpecialProvisions

Exposure controls / personal protection

· General protective and hygienic measures

Keep away from foodstuffs, beverages and food.

Do not eat, drink or smoke while working.

Instantly remove any contaminated garments.

Do not breathe dust.

Avoid close or long term contact with the skin.

Avoid contact with the eyes.

Wash hands during breaks and at the end of the work.

· Personal protective equipment

· Breathing equipment:

Use breathing protection in case of dust formation.

Filter P2.

· Protection of hands:

Protective gloves

To avoid skin problems reduce the wearing of gloves to the required minimum.

Check the permeability prior to each renewed use of the glove.

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation.

· Material of gloves

Nitrile rubber - NBR

Recommended thickness of the material: ≥ 0,11 mm

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality

and varies from manufacturer to manufacturer.

· Penetration time of glove material

Penetration time: ≥ 8 hours

The exact break through time has to be found out by the manufacturer of the protective gloves and has to be

observed.

Protective gloves should be replaced at first signs of wear.

· Eye protection: Safety glasses

· Body protection: Protective work clothing

Stability and reactivity

· Thermal decomposition / conditions to be avoided:

Avoid impact, friction, heat, sparks, electrostatic charges.

· Materials to be avoided: Strong oxidizing agents

· Dangerous reactions Violent reaction with strong oxidizing agents.

· Dangerous products of decomposition:

Nitrogen oxides (NOx)

Carbon monoxide (CO) and Carbon dioxide (CO₂)

Disposal considerations

· Recommendation Disposal must be made according to official regulations.

· European waste catalogue:

Waste disposal key numbers from EWC have to be assigned depending on origin and processing.

· Uncleaned packagings:

· Recommendation: Disposal must be made according to official regulations.