Registration Dossier

Classification & Labelling & PBT assessment

GHS

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General Information

Implementation:
EU
Type of classification:
self-classification
Remarks:

This C&L information includes all of the harmonized classification information provided for this substance in Annex VI in the EU Regulation 1272/2008 (CLP) and includes addtionally a self-declaration with EUH071 "corrosive to the respiratory tract" and a environmental hazard classification as Aquatic Chronic 3, H412.

Index-Nr.: 612-001-00-9; di-methylamine

Flam. Gas 1, H220

Press. Gas

Acute Tox. 4 *, H332

STOT SE 3, H335

Skin Irrit. 2, H315

Eye Dam. 1, H318

SCL: Skin Irrit.; H315: C ≥ 5 %, Eye Dam. 1; H318: C ≥ 5 %, Eye Irrit. 2; H319: 0,5 % ≤ C < 5 %, STOT SE 3; H335: C ≥ 5 %

Related composition

Related composition:
Dimethylamine
Dimethylamine

Classificationopen allclose all

Explosives
Reason for no classification:
hazard class not applicable
Flammable gases and chemically unstable gases
Hazard category:
Flam. Gas 1A
Hazard statement:
H220: Extremely flammable gas.
Aerosols
Reason for no classification:
hazard class not applicable
Reason for no classification:
hazard class not assessed
Oxidising gases
Reason for no classification:
data conclusive but not sufficient for classification
Gases under pressure
Hazard category:
Liquefied gas
Hazard statement:
H280: Contains gas under pressure; may explode if heated.
Flammable liquids
Reason for no classification:
hazard class not applicable
Flammable solids
Reason for no classification:
hazard class not applicable
Self-reactive substances and mixtures
Reason for no classification:
hazard class not applicable
Pyrophoric liquids
Reason for no classification:
hazard class not applicable
Pyrophoric solids
Reason for no classification:
hazard class not applicable
Self-heating substances and mixtures
Reason for no classification:
hazard class not applicable
Substances and mixtures which in contact with water emit flammable gases
Reason for no classification:
hazard class not applicable
Oxidising liquids
Reason for no classification:
hazard class not applicable
Oxidising solids
Reason for no classification:
hazard class not applicable
Organic peroxides
Reason for no classification:
hazard class not applicable
Corrosive to metals
Reason for no classification:
data conclusive but not sufficient for classification
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Reason for no classification:
data conclusive but not sufficient for classification
Acute toxicity - dermal
Reason for no classification:
data conclusive but not sufficient for classification
Acute toxicity - inhalation
Hazard category:
Acute Tox. 4
Hazard statement:
H332: Harmful if inhaled.
Skin corrosion / irritation
Hazard category:
Skin Irrit. 2
Hazard statement:
H315: Causes skin irritation.
Serious eye damage / eye irritation
Hazard category:
Eye Damage 1
Hazard statement:
H318: Causes serious eye damage.
Respiratory sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Skin sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Aspiration hazard
Reason for no classification:
data conclusive but not sufficient for classification
Reproductive toxicity
Reason for no classification:
data conclusive but not sufficient for classification
Effects on or via lactation
Reason for no classification:
data conclusive but not sufficient for classification
Germ cell mutagenicity
Reason for no classification:
data conclusive but not sufficient for classification
Carcinogenicity
Reason for no classification:
data conclusive but not sufficient for classification
1. Specific target organ toxicity - single (STOT-SE)
Hazard category:
STOT Single Exp. 3
Hazard statement:
H335: May cause respiratory irritation.
Affected organs:
other: respiratory tract, lungs
Route of exposure:
inhalation
1. Specific target organ toxicity - repeated (STOT-RE)
Reason for no classification:
data conclusive but not sufficient for classification
1.
Concentration range (%):
>= 0.5 - < 5
Hazard categories:
Eye Irrit. 2
2.
Concentration range (%):
>= 5
Hazard categories:
Eye Damage 1
STOT Single Exp. 3
Skin Irrit. 2
Hazardous to the aquatic environment (acute / short-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the aquatic environment (long-term)
Hazard category:
Aquatic Chronic 3
Hazard statement:
H412: Harmful to aquatic life with long lasting effects.
Hazardous to the ozone layer
Reason for no classification:
data conclusive but not sufficient for classification
Additional hazard statements:
For Eye Irrit.2 (0.5 % <= C < 5 %): H319: Causes serious eye irritation;
For Eye Damage 1 (C >= 5 %): H318: Causes serious eye damage;
For Skin Irrit.2 (C >= 5 %): H315: Causes skin irritation.
For STOT SE 3 (C>=5%): H335: May cause respiratory irritation.

Labelling

Signal word:
Danger

Hazard pictogram

GHS02: flame
GHS04: gas cylinder
GHS05: corrosion
GHS07: exclamation mark

Hazard statements

H220: Extremely flammable gas.
H280: Contains gas under pressure; may explode if heated.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H412: Harmful to aquatic life with long lasting effects.

Precautionary statements

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P273: Avoid release to the environment.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/…
P362+P364: Take off contaminated clothing and wash it before reuse.
P405: Store locked up.
P410+P403: Protect from sunlight. Store in a well-ventilated place.
P501: Dispose of contents/container to ...

Additional labelling requirements

EUH071: Corrosive to the respiratory tract.
The data for DMA indicate that the mechanism of toxicity is corrosivity, as such this additional labelling shall also be applied.

Notes