Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures

General advice: Take off all contaminated clothing immediately.Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.

Inhalation : Move subject to fresh air and keep him calm. Call a physician immediately.

Skin contact : Wash off immediately with soap and water. See a physician.

Eye contact : Flush eyes thoroughly with a large amount of water and consult a physician.
Ingestion : Do not induce vomiting. Call a physician immediately.

4.2. Most important symptoms and effects, both acute and delayed

Headache, Vertigo, difficulty breathing, Nausea, Gastrointestinal discomfort

4.3. Indication of any immediate medical attention and special treatment needed

No specific antidote known.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media:
foam
dry chemical
carbon dioxide

Unsuitable extinguishing media:
High volume water jet

5.2. Special hazards arising from the substance or mixture

Closed container may rupture if strongly heated.
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.


5.3. Advice for firefighters

Wear self-contained breathing apparatus.

Containers exposed to heat (fire) may build up pressure. Cool by splashing with water.
Fire residues should be disposed of in accordance with the regulations. Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Assure sufficient ventilation.
Use personal protective clothing.
Keep away sources of ignition.
Use breathing apparatus if exposed to vapours/dust/mist/aerosol.

6.2. Environmental precautions

Prevent product from getting into drains/surface water/groundwater.
If the product contaminates rivers and lakes or drains inform respective authorities.

6.3. Methods and material for containment and cleaning up

Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment!
Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust).
Dispose of in accordance with regulations.

Handling and storage

7.1. Precautions for safe handling

Safe handling advice:
Provide good room ventilation even at ground level (vapours are heavier than air). Keep container tightly closed.

Advice on protection against fire and explosion:
Keep away from sources of ignition --- No smoking. Take precautionary measures against static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air.


7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers:
Keep only in the original container at a temperature not exceeding 30 °C. Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Protect from the action of light. Can polymerize with intense heat release.


7.3. Specific end use(s)
no

Transport information

Land transport (ADR/RID)

UN number:
UN 2929
Proper shipping name and description:
UN 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (contains allyl methacrylate, stabilized), 6.1 (3), II, (D/E),
Environmentally Hazardous
Hazard no. 63
Chemical name:
allyl methacrylate, stabilized
Language:
English
Class:
6.1
Classification code:
3
Packaging group:
II
Labels:
(D/E),
Environmentally Hazardous
Hazard no. 63
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 2929
Shippingopen allclose all
Class:
6.1
Classification code:
3
Packaging group:
II
Labels:
Environmentally Hazardous
Hazard no. 63
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 2929
Proper shipping name and description:
TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (contains allyl methacrylate,
stabilized)
Chemical name:
allyl methacrylate, stabilized
Class:
6.1
Packaging group:
II
EmS code:
F-E, S-D
Labels:
Hazardous constituent allyl methacrylate, stabilized
Marine pollutant
Remarks
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code:
for transportapproval see regulatory information

Air transport ICAO/IATA

UN number:
UN 2929
Proper shipping name and description:
TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (contains allyl methacrylate,
stabilized)
Chemical name:
allyl methacrylate, stabilized
Class:
6.1
Packaging group:
II
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters
see section 8.2.

8.2. Exposure controls
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health

DNEL
Critical component Routes of exposure Workers Industry / trade Note
allyl methacrylate Inhalation 1.47 mg/m3 Long-term - systemic effects
allyl methacrylate Inhalation 7.35 mg/m3 Acute - systemic effects
allyl methacrylate dermal 0.58 mg/kg bodyweight/day Long-term - systemic effects
allyl methacrylate dermal 2.9 mg/kg bodyweight/day Acute - systemic effects

PNEC
Critical component Routes of exposure Workers Industry / trade Note
allyl methacrylate Freshwater 0.00272 mg/l
allyl methacrylate marine water 0.000272 mg/l
allyl methacrylate sewage treatment plant (STP) 10 mg/l
allyl methacrylate Soil 0.00619 mg/kg
allyl methacrylate Fresh water sediment 0.0389 mg/kg dry weight
allyl methacrylate marine water sediment 0.00389 mg/kg dry weight


Protective measures
Do not breathe vapours. Avoid contact with eyes and skin. Do not eat, drink or smoke during use.

Hygiene measures
Store work clothing separately. Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.

Respiratory protection
Breathing apparatus in case of high concentrations, short term: filter appliance, filter A

Hand protection:
Glove material: butyl-rubber
Break through time: 60 min
Glove thickness: 0.3 mm
EN 374
The above mentioned hand protection is based on special knowledge of the chemical and the intended handling of this product, however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine the suitability of gloves for specific working environments and processes.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

General information
Gloves should be replaced regularly, especially after extended contact with the product. For each work-place a suitable glove type has to be selected.

Eye protection
tightly fitting goggles

Skin and body protection
On handling of larger quantities: face mask, chemical-resistant boots and apron

Stability and reactivity

10.1. Reactivity
see section 10.2.

10.2. Chemical stability
No decomposition if used as directed.

10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.

10.4. Conditions to avoid
Avoid high temperatures and sources of ignition.
Ultraviolet light.
The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.

10.5. Incompatible materials
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents.

10.6. Hazardous decomposition products
None when used as directed.

Disposal considerations

13.1. Waste treatment methods
Product
Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility.

Uncleaned packaging
Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated. Packaging that cannot be cleaned should be disposed of professionally. Uncontaminated packaging may be taken for recycling.

Code of waste EWC
07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics, synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.