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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Additional physico-chemical information

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Administrative data

Endpoint:
other:
Type of information:
other: handbook data
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Handbook data considered to be from a trusted source acc. to "ECHA, Guidance on information requirements and chemical safety assessment – Chapter R.7a: Endpoint specific guidance".

Data source

Reference
Reference Type:
review article or handbook
Title:
Bretherick`s - Handbook of reactive chemical hazards
Author:
Urben, P.G.
Year:
2007
Bibliographic source:
Academic press - Elsevier, 7. Edition, Vol. 1

Materials and methods

Test guideline
Qualifier:
no guideline followed
Principles of method if other than guideline:
Reaction of DMS with conc. aqueous ammonia
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Dimethyl sulphate
EC Number:
201-058-1
EC Name:
Dimethyl sulphate
Cas Number:
77-78-1
Molecular formula:
C2H6O4S
IUPAC Name:
dimethyl sulfate

Results and discussion

Results:
A violent reaction occured which shattered the flask when litre quantities of DMS and conc. aqueous ammonia were accidentally mixed. Similar incidents were noted with other bases.

Applicant's summary and conclusion