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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Link to relevant study record(s)

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Endpoint:
pyrophoric liquids
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
the study does not need to be conducted because the substance is pyrophoric
Endpoint:
substances / mixtures which in contact with water emit flammable gases
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
other:
Endpoint:
self-heating substances / mixtures
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is pyrophoric
Endpoint:
flammable solids
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is a liquid
Conclusions:
Determination of flammability is not required for zinc alkyls due to
their pyrophoric nature.

Description of key information

The endpoint is waived, the substance is a pyrophoric and explosively water reactive (emitting ethane) substance.

Key value for chemical safety assessment

Flammability:
pyrophoric

Additional information

According to the Annex VII Standard Information Requirements for REACH, determination of flammability is required. Column 2 - specific rules for adaption from column 1 - states that flammability determination does not need to be conducted in case the substance is pyrophoric. Zinc alkyls are highly reactive both towards oxygen (air) and water as explained below. They are exclusively marketed in liquid state and shipped under UN transport class 4.2 (substances liable to spontaneous combustion / pyrophoric liquids) or at least under class 4.3 (substances which in contact with water emit flammable gases).

Justification for classification or non-classification

The substance is harmonized as a pyrophoric and water reactive liquid