Reaction mass of 3-isopropyl-6-methylenecyclohexene and (4R)-1-methyl-4-(prop-1-en-2-yl)cyclohexene and (4S)-1-methyl-4-(prop-1-en-2-yl)cyclohexene

Guidance on Safe Use

First-aid measures

After inhalation:

Supply fresh air. If symptoms are experienced, get medical attention.

In case of unconsciousness place patient stably in side position for transportation.

After skin contact:

Immediately rinse with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation or skin rash occurs.

After eye contact:

Immediately rinse with plenty of water. Remove contact lenses, if present and easy to do. Hold eyelids apart and flush

eyes with plenty of cool low-pressure water for 15 minutes. Consult an ophthalmologist.

After ingestion:

Do NOT induce vomiting. If person is conscious, rinse out mouth with water. Call for a doctor immediately.

Most important symptoms and effects, both acute and delayed:

Pulmonary effects if swallowed accidentally.

Indication of any immediate medical attention and special treatment needed:

If swallowed accidentally, medical survey for 48 hours minimum.

Fire-fighting measures

Suitable extinguishing agents:

CO2, foam, powder.

Special hazards arising from the substance or mixture: In case of fire, may release irritant and toxic fumes.

Special protective equipment for fire-fighters:

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus.

Additional information:

Cool endangered receptacles with water spray.

Accidental release measures

Person-related safety precautions:

Wear appropriate personal protective equipment. Keep unprotected persons away. Provide adequate ventilation. Keep away from sources of ignition.

Measures for environmental protection:

Do not allow product to reach soil, waterways, drains and sewers.

Inform the relevant authorities if the product has caused environmental pollution (soil, waterways, drains or sewers).

Measures for cleaning/collecting:

Small spills: Absorb spilled liquid with inert absorbent. Collect in an appropriate container properly labelled. Close it for disposal.

Large spills: Stop spill if it can be done without danger. Dike. Pump as much liquid as possible with an explosion-proof pump or a hand pump. Absorb the remaining liquid with inert absorbent. Collect in an appropriate container properly labelled. Close it for disposal. Use only non-sparking tools.

Handling and storage

Handling:

Wear appropriate personal protective equipment. Provide adequate ventilation in the workplace.

Use suitable respiratory protective device in case of insufficient ventilation.

Information about fire - and explosion protection:

Protect against electrostatic charges. Use only non-sparking tools. Keep ignition sources away. Protect from heat.

Conditions for safe storage:

Store if possible under cover in a dry, cool and well-ventilated area. Keep container tightly sealed.

All equipments including ventilation systems must be equipotential and earthed.

Keep away from sources of ignition. Protect from heat and direct sunlight.

Recommended and Unsuitable Materials for Storage :

- Stainless steel, aluminium

- Certain plastics and elastomers may not be compatible with the product.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

2319

Shipping information

Proper shipping name and description:

TERPENE HYDROCARBONS, N.O.S (mixture dipentene), ENVIRONMENTALLY HAZARDOUS

Language:

English

Labels:

3

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

2319

Shipping information

Proper shipping name and description:

TERPENE HYDROCARBONS, N.O.S (dipentene), ENVIRONMENTALLY HAZARDOUS

Language:

English

Labels:

3

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

2319

Shipping information

Proper shipping name and description:

TERPENE HYDROCARBONS, N.O.S (dipentene), ENVIRONMENTALLY HAZARDOUS

Labels:

3

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

2319

Shipping information

Proper shipping name and description:

TERPENE HYDROCARBONS, N.O.S (dipentene), ENVIRONMENTALLY HAZARDOUS

Labels:

3

Remarks

SpecialProvisions

Exposure controls / personal protection

Engineering measures:

The usual precautionary measures are to be adhered to when handling chemicals. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.

Immediately remove all soiled and contaminated clothing.

Avoid contact with eyes and skin.

Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation.

Hand protection:

Protective gloves resistant to chemicals (standard EN 374-1). They should be replaced regularly and if there is any

indication of degradation or chemical breakthrough.

Eye protection: Safety glasses (standard EN 166).

Body protection:

Protective work clothing.

Stability and reactivity

Reactivity:

No data from specific reactivity tests are available for this product or this class of product.

Chemical stability

Product stable under storage and handling conditions according to specifications.

Possibility of hazardous reactions

No hazardous reactions known except those with incompatible products below.

Conditions to avoid

Keep away from any flame or source of sparks.

Incompatible materials:

Strong acids and strong oxidising agents.

Hazardous decomposition products:

No dangerous decomposition products known.

Disposal considerations

Waste treatment methods: National and regional regulations have to be adhered to.

The product has to be disposed of in an authorised incinerator, according to regulation.

Uncleaned packaging:

Packaging has to be sent to an authorised waste treatment facility, for recycling or disposal.