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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Explosiveness

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Description of key information

Loose heaped powder is not explosive but might get subject to dust explosions by being dispersed in mixture with air.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Loose heaped red phosphorus powder itself is not explosive even so it can be ignited by very small ignition energies and burns with a fast deflagration (see CSR Chapter 6.2.).

But dust clouds of red phosphorus powder in air are highly explosive with a high maximum rate of pressure rise and a very small minimum ignition energy (see CSR chapter 6.4) leading to the highest classification of the dust explosion class (3).

Justification for classification or non-classification

Red phosphorus in form of pure loose heaped powder is classified as non explosive, because even so it can be ignited by very small energies it just burns with a burning rate typical for a highly flammable substance without any explosion.

This behaviour changes in contact with oxidising substances. Such mixtures might already explode by applying small energies. This behaviour is well known because such mixtures are used in the ammunition industry.