Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

Currently viewing:

Administrative data

First-aid measures

General advice : Immediate medical attention is required. Move out of dangerous area. Show this safety data sheet to the doctor in attendance.
Inhalation : If breathed in, move person into fresh air. Consult a physician after significant exposure. Skin contact : Take off contaminated clothing and shoes immediately. Rinse immediately with plenty of water. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If skin irritation persists, call a physician. Eye contact : Get medical attention immediately. Continue to rinse during transport. Remove contact lenses. Protect unharmed eye. Small amounts splashed into eyes can cause irreversible tissue damage and blindness. Ingestion : Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person.
Take victim immediately to hospital. Do not induce vomiting! May cause chemical burns in mouth and throat.

Fire-fighting measures

Suitable extinguishing media : Dry chemical Alcohol-resistant foam Specific hazards during fire fighting : Treat as oil fire. Water spray may be ineffective unless used by experienced firefighters. Do not allow run-off from fire fighting to enter drains or water courses. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments.

Accidental release measures

Personal precautions : For personal protection see section 8. Use personal protective equipment. Ensure adequate ventilation. Environmental precautions : Do not flush into surface water or sanitary sewer system. Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

Handling and storage

Handling Advice on safe handling : Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. Advice on protection against fire and explosion : Avoid formation of aerosol. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers : No smoking.
Keep container tightly closed in a dry and well-ventilated place. Reacts with copper, aluminium, zinc and their alloys. Other data : No decomposition if stored and applied as directed.

Transport information

Land transport (ADR/RID)

UN number:
2734
Shippingopen allclose all
Class:
8
Classification code:
CF1
Packaging group:
II
Labels:
8 (3)
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2734
Shippingopen allclose all
Class:
8
Classification code:
CF1
Packaging group:
II
Labels:
8 (3)
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2734
Proper shipping name and description:
Amines, liquid, corrosive, flammable, n.o.s.
(N-Methyl piperazine)
Chemical name:
N-Methyl piperazine
Class:
8
Packaging group:
II
EmS code:
F-E, S-C
Labels:
8 (3)
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2734
Proper shipping name and description:
Amines, liquid, corrosive, flammable, n.o.s.
(N-Methyl piperazine)
Chemical name:
N-Methyl piperazine
Class:
8
Packaging group:
II
Labels:
8 (3)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering Controls
Ensure that eyewash stations and safety showers are close to the workstation location. Effective exhaust ventilation system
Personal protective equipment
Respiratory protection : In the case of vapour formation use a respirator with an approved filter.
Hand protection : Glove material: butyl-rubber
Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems.Skin and body protection : Protective suit Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Wash contaminated clothing before re-use.

Stability and reactivity

Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong acids and oxidizing agents Halogenated compounds Reacts with copper, aluminium, zinc and their alloys. Hazardous decomposition products : No hazardous decomposition products are known. Thermal decomposition : Heating can release hazardous gases., nitrogen oxides (NOx) Hazardous reactions : Stable under normal conditions.

Disposal considerations

Product : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Hazardous waste
Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.