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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Ecotoxicological information

Toxicity to soil macroorganisms except arthropods

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Administrative data

Link to relevant study record(s)

Description of key information

Hydrogen sulfide and Ba will be released from BaS under normal environmental conditions. No data for sulfide are identified for this endpoint, and are not required if indirect exposure of the soil compartment is unlikely. For barium, the NOEC values of 258 and 433 mg Ba/kg soil dw were put forward for the derivation of a terrestrial PNEC. Expressed as BaS, these values become 318.2 mg BaS/kg soil dw and 534.1 mg BaS/kg soil dw, respectively.

Key value for chemical safety assessment

Long-term EC10, LC10 or NOEC for soil macroorganisms:
318.2 mg/kg soil dw

Additional information

Sulfide: According to Column 2 of Annex IX of the REACH regulation, these studies do not need to be conducted if direct and indirect exposure of the soil compartment is unlikely. Because all identified uses are industrial indoor (or enclosed) processes, no release of the substances to soil is expected. As Na2S and NaHS are not expected to occur as such in soil because of hydrolysis and/or oxidation and/or precipitation processes, no terrestrial toxicity studies can be conducted using the compounds as such.

Barium: Kuperman et al (2008) reported reliable NOEC-values (added as barium nitrate) for twodifferent soil macro-organisms (E. fetida, E. crypticus). The derived effect values were based on ecological relevant endpoints (mortality and reproduction). Reproduction was the most sensitive endpoint, and NOEC-values were 258 and 433 mg Ba/kg soil dw for E. fetida and E. crypticus, respectively. Expressing these values based on the substance (BaS), these NOECs become 318.2 mg BaS/kg soil dw and 534.1 mg BaS/kg soil dw, respectively.