Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

- After inhalation:
If breathed in, move person into fresh air. Seek medical attention if respiratory irritation develops or if breathing becomes difficult.

- After skin contact:
After contact with skin, wash immediately with plenty of soap and water. If skin irritation persists, call a physician.

- After eye contact:
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

- After swallowing:
Do not induce vomiting without medical advice. Immediately give large quantities of water to drink. Call a physician immediately.
Never give anything by mouth to an unconscious person.

Fire-fighting measures

- Suitable extinguishing agents:
Use dry chemical or foam.

- Unsuitable extinguishing media:
water

- Special hazards caused by the material, its products of combustion or resulting gases:
carbon oxides (COx), nitrogen oxides (NOx), suphur oxides (SOx)

Advice for firefighters:
- Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
In the event of fire, wear self-contained breathing apparatus.
Use water spray to cool unopened containers.

- Further information:
Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Avoid contact with spilled product or contaminated surfaces.
Use personal protective equipment.

Environmental precautions:
Do not allow to get into surface water, drains and ground water.

Methods and materials for containment and cleaning up:
- Methods for cleaning up:
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Clean contaminated floors and objects thoroughly, observing environmental regulations.
Keep in suitable, closed containers for disposal.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.

Precautions for safe handling:
- Advice on safe handling:
Use only in area provided with appropriate exhaust ventilation.

- Advice on protection against fire and explosion:
No special precautions required.

- Hygiene measures:
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Wash hands before breaks and immediately after handling the product.
Remove soiled clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).

Conditions for safe storage, including any incompatibilities:
- Requirements for storage areas and containers:
Store in original container.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Store in a place accessible by authorized persons only.

- Advice on common storage:
Keep away from food, drink and animal feedingstuffs.

Transport information

Land transport (ADR/RID)

UN number:
3080
Proper shipping name and description:
UN 3080, ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.
(METHYL-4-(AMINOSULFONYL)-5-METHYLTHIOPHENE-3-CARBOXYLATE, XYLENE SOLUTION)
Chemical name:
methyl 5-methyl-4-[(oxomethylene)sulfamoyl]thiophene-3-carboxylate
Language:
English
Class:
6.1
Classification code:
TF1
Packaging group:
II
Labels:
6.1, 3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3080
Proper shipping name and description:
UN 3080, ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.
(METHYL-4-(AMINOSULFONYL)-5-METHYLTHIOPHENE-3-CARBOXYLATE, XYLENE SOLUTION)
Chemical name:
methyl 5-methyl-4-[(oxomethylene)sulfamoyl]thiophene-3-carboxylate
Language:
English
Class:
6.1 (3)
Classification code:
TF1
Packaging group:
II
Labels:
6.1, 3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3080
Proper shipping name and description:
UN 3080, ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.
(METHYL-4-(AMINOSULFONYL)-5-METHYLTHIOPHENE-3-CARBOXYLATE, XYLENE SOLUTION)
Chemical name:
methyl 5-methyl-4-[(oxomethylene)sulfamoyl]thiophene-3-carboxylate
Class:
6.1 (3)6.1 (3)
Packaging group:
II
EmS code:
F-E, S-D
Labels:
6.1, 3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3080
Proper shipping name and description:
UN 3080, ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.
(METHYL-4-(AMINOSULFONYL)-5-METHYLTHIOPHENE-3-CARBOXYLATE, XYLENE SOLUTION)
Chemical name:
methyl 5-methyl-4-[(oxomethylene)sulfamoyl]thiophene-3-carboxylate
Class:
6.1 (3)
Packaging group:
II
Labels:
6.1, 3
Remarksopen allclose all

Additional transport information

Additional transport information
The substance is only transported in solution.

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.


Personal protective equipment:
- Respiratory protection:
In the case of vapour formation use a respirator with an approved filter.
Respirator with a vapour filter (EN 141) Respirator with ABEK filter.

- Hand protection:
Suitable material : Nitrile rubber, Break through time : > 480 min
Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).

- Eye protection:
Tightly fitting safety goggles

- Skin and body protection:
Choose body protection according to the amount and concentration of the dangerous substance at the work place.
No special protective equipment required.

Stability and reactivity

Chemical stability:
Stable under recommended storage conditions.

Materials to avoid:
water, oxidizing agents

Possibility of hazardous reactions:
Reacts violently with water

Conditions to avoid:
Keep away from sources of ignition.
Protect from moisture.
Extremes of temperature and direct sunlight.

Disposal considerations

During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken. The substance is handled under strictly controlled conditions.

Dispose in accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the
product may be taken to a waste disposal site or incineration plant.