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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice:
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). First aid personnel should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention

Fire-fighting measures

Suitable extinguishing media:
water spray, dry powder, foam
Unsuitable extinguishing media for safety reasons:
water jet
Specific hazards:
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions:
Use personal protective clothing. Breathing protection required.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up or taking up:
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.

Handling and storage

Precautions for safe handling:
Use with local exhaust ventilation. Provide extract ventilation to points where emissions occur (LEV). Avoid contact with the skin, eyes and clothing. Provide specific employee training to
prevent/minimize exposures.
Protection against fire and explosion:
Take precautionary measures against static discharges.
Conditions for safe storage, including any incompatibilities:
Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place. The packed product is not damaged by low temperatures or by frost.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3082
Shippingopen allclose all
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE)
Special provisions / remarks
Remarks:
None known

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3082
Shippingopen allclose all
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE)
Special provisions / remarks
Remarks:
None known

Marine transport (UN RTDG/IMDG)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE
Chemical name:
BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE, METHYL 1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL SEBACATE
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE
Marine pollutant
Special provisions / remarks
Remarks:
None known

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE
Chemical name:
BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE, METHYL 1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL SEBACATE
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL)SEBACATE
Special provisions / remarks
Remarks:
None known
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Gas filter for
gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Wear chemically resistant gloves in combination with specific activity training
Chemical resistant protective gloves (EN ISO 374-1)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN ISO 374-1):
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
chemical-protection suit (f.e. according to EN 14605)
General safety and hygiene measures
Wearing of closed work clothing is required additionally to the stated personal protection equipment.
Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
Do not discharge product into the environment without control.

Stability and reactivity

Reactivity:
No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: No corrosive effect on metal. Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
Chemical stability:
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions: No hazardous reactions when stored and handled according to instructions.
Conditions to avoid:
Avoid all sources of ignition: heat, sparks, open flame. Avoid electro-static discharge.
Incompatible materials:
Substances to avoid: strong acids, strong bases, strong oxidizing agents
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods:
Must be disposed of or incinerated in accordance with local regulations. Waste key: 07 02 08¤ other still bottoms and reaction residues
Contaminated packaging:
Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents.