Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice:
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and
transport in stable sideways position (recovery position). First aid personnel should pay attention to
their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale corticosteroid dose
aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Note to physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.

Fire-fighting measures

Suitable extinguishing media:
dry extinguishing media, foam, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water
Specific hazards:
hydrogen chloride (HCl)
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

Personal precautions:
Breathing protection required. Avoid contact with the skin, eyes and clothing.
Environmental precautions:
Do not empty into drains.
Methods for cleaning up or taking up:
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of absorbed material in accordance with regulations.

Handling and storage

Handling
Ensure thorough ventilation of stores and work areas. Protect against moisture. Protect against heat.
Protection against fire and explosion:
Take precautionary measures against static discharges. Substance/product is a flammable liquid.
Storage
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Protect against moisture. Protect against heat. Storage at a proportionate temperature is required, to
avoid 'breathing' of containers.
Storage stability:
Storage duration: 12 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Personal protective equipment
Respiratory protection:
Breathing protection if gases/vapours are formed. Self-contained breathing apparatus.
Hand protection:
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
nitrile rubber (NBR) - 0.4 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures:
Avoid contact with the skin, eyes and clothing. Avoid inhalation of vapour.

Stability and reactivity

Substances to avoid:
water, bases, amines, amine compounds
Hazardous reactions:
Strong exothermic reaction.
Hazardous decomposition products:
hydrogen chloride

Disposal considerations

Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling
after being thoroughly cleaned.