Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures:

Skin: Wash affected areas with water while removing contaminated clothing. Get immediate medical attention.
Eyes: Flush eyes with generous amounts of water for at least 15 minutes. Get immediate medical attention.
Ingestion: If swallowed, immediately induce vomiting unless the victim is unconscious. Dilute with water or milk and call a physician immediately.
Inhalation: Move to fresh air. Aid in breathing, if necessary and get immediate medical attention.

Most important symptoms and effects, both acute and delayed:

No significant reaction of the human body to this substance is known.

Indication of any immediate medical attention and special treatment needed:

There is no specific and immediate treatment. Consultation with a doctor is recommended.

Fire-fighting measures

Extinguishing media: Water spray, dry chemical, foam or carbon dioxide.

Special hazards arising from the substance: Toxic gases will form upon combustion; oxides of carbon and nitrogen

Advice for firefighters: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Shut off all sources of ignition - heat, sparks, open flame.

Accidental release measures

Environmental precautions: Do not discharge into sewage / drainage system.

Methods and material for containment and cleaning up: Sweep up, place in a bag and hold for waste disposal. Consult a specialist waste disposal firm for disposal of recovered material. Remove any leaking containers to a safe place, if feasible.

Handling and storage

Precautions for safe handling: Use only in well-ventilated areas. Do not breathe dust. Keep container tightly closed. Avoid contact with skin or eyes. Wash thoroughly after handling. When using do not eat or drink.

Conditions for safe storage, including any incompatibilities: Keep containers upright and tightly closed when not in use. Keep away from heat, steam pipes or sunlight. Store in a cool, dry, well-ventilated location.

Conditions to avoid: Water, humidity, ignition sources, high temperatures.

Transport information

Land transport (ADR/RID)

UN number:
Not classified for transportation providing the packed volume is less than 450 litres.
If the packed volume is 450 litres or greater UN number 3088 should be assigned.
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Class:
4.2 if the packed volume if 450 litres or greater.
Classification code:
4.2 if the packed volume if 450 litres or greater.
Packaging group:
III if the packed volume if 450 litres or greater.
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Inland waterway transport (ADN(R))

UN number:
Not classified for transportation providing the packed volume is less than 450 litres.
If the packed volume is 450 litres or greater UN number 3088 should be assigned.
Shippingopen allclose all
Class:
4.2 if the packed volume if 450 litres or greater.
Classification code:
4.2 if the packed volume if 450 litres or greater.
Packaging group:
III if the packed volume if 450 litres or greater.
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Marine transport (IMDG)

UN number:
Not classified for transportation providing the packed volume is less than 450 litres.
If the packed volume is 450 litres or greater UN number 3088 should be assigned.
Proper shipping name and description:
Self-heating solid, organic, n.o.s. (If the packed volume is 450 litres or greater)
Chemical name:
Benzenamine, reaction products with aniline hydrochloride and nitrobenzene
Class:
4.2 if the packed volume if 450 litres or greater.
Packaging group:
III if the packed volume if 450 litres or greater.
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Air transport ICAO/IATA

UN number:
Not classified for transportation providing the packed volume is less than 450 litres.
If the packed volume is 450 litres or greater UN number 3088 should be assigned.
Proper shipping name and description:
Self-heating solid, organic, n.o.s. (If the packed volume is 450 litres or greater)
Chemical name:
Benzenamine, reaction products with aniline hydrochloride and nitrobenzene
Class:
4.2 if the packed volume if 450 litres or greater.
Packaging group:
III if the packed volume if 450 litres or greater.
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters: There are no specific control parameters for this substance.

Exposure controls: Use local exhaust ventilation.
Emissions form ventilation or work process equipment should be checked to ensure they comply with the local or national requirements.

Personal precautions, protective equipment:

Respiratory protection: NIOSH/MSHA-approved dust respirator
Eye protection: Chemical safety goggles
Hand, skin and body protection: Gloves, coveralls, apron, boots as necessary to avoid skin contact

Stability and reactivity

Self-heating: The substance is classified as a self-heating substance category 2 if packaged in volumes of 450 litres or greater.

Reactivity: No hazardous reactions if stored and handled as prescribed.

Chemical stability: This substance is chemically stable if stored and handled as prescribed.

Possibility of hazardous reactions: No hazardous reactions known.

Incompatible materials: Strong oxidisers, strong bases.

Hazardous decomposition products: Evolves oxides of carbon and nitrogen on combustion.

Disposal considerations

Waste treatment methods: Burn in a chemical incinerator equipped with an afterburner.