Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Using appropriate personal protective equipment, move
exposed subject to fresh air. If breathing is difficult or
ceases, ensure and maintain ventilation. Give oxygen as
appropriate. The exposed subject should be kept warm and at
rest. Obtain medical attention in cases of known or possible
over exposure, or with symptoms including chest pain,
difficulty breathing, loss of consciousness or other adverse
effects, which may be delayed.
Emergency measure - Eyes: Wash immediately with clean and gently flowing water.
Continue for at least 15 minutes. Obtain medical attention.
Emergency measure - Skin: Using appropriate personal protective equipment, remove
contaminated clothing and flush exposed area with large
amounts of water. Obtain medical attention if skin reaction
occurs, which may be immediate or delayed.
Emergency measure - Ingestion: Never attempt to induce vomiting. Do not attempt to give any
solid or liquid by mouth if the exposed subject is
unconscious or semi-conscious. Wash out the mouth with
water. If exposed subject is fully conscious, give plenty of
water to drink. Obtain medical attention.

Fire-fighting measures

Recommended extinguishing agent: Water, dry powder or foam extinguisher.

Product arising from burning: The substance is combustible and will burn if involved in
a fire, evolving noxious fumes (eg carbon and nitrogen
oxides and halogen containing compounds).

Product determined by test: N

Protective equipment: Full protective clothing and self-contained breathing
apparatus must be worn.


Fight the fire from a safe distance or protected location.

Accidental release measures

Emergency measures in case of spillage: Evacuate personnel from immediate vicinity.


Wear appropriate personal protective equipment conforming to
the relevant national or international standards, as
mentioned in section 2.3.10.


Avoid dust formation. Absorb spillages of solutions with a
suitable inert material (eg. sand or soil).
Carefully transfer the spillage to waste containers, or use
a sealed


industrial vacuum machine. Containers filled with waste
material must be labelled in the same way as the original
substance containers.


Clean the spillage area with water only if waste water can
be directed to an on-site waste water treatment system.




Dispose of waste material in accordance with local
regulations by incineration.

Handling and storage

Handling: The substance should be stored, handled and used under
conditions of good industrial hygiene and in conformity with
any local regulations in order to avoid exposure.



Engineering controls are necessary to reduce exposure to the
substance. These include a glovebox during charging and
laminar flow booths during sampling, dispensing and
laboratory handling.



When exposure cannot be prevented or adequately controlled
appropriate personal protective equipment should be worn.

Such protective equipment should conform to the appropriate
international or national standards and include a powered
air hood and tyvek suit.



Furthermore, when respiratory protective equipment has to be
used, it must be capable of adequately controlling
exposure, be suitable for the purpose, and conform to the
appropriate international or national standards, such as
Respirex EN Standard 943 Part I Airhood.



These measures should be regarded as a minimum.

Storage: Store away from moisture and sources of ignition.



Keep containers tightly closed when not in use.

Packaging of the substance and or preparation: Double-lined fibre keg. 20 kg of material per bag.

Transport information

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Marine transport (UN RTDG/IMDG)

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Air transport (UN RTDG/ICAO/IATA)

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Special provisions / remarks
Remarks:
Transport code: UN 3077, Class 9, Packing group 3
Transport: Avoid crushing the containers. In the event of a spillage,
observe the warning labels on the container.
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: None.

Chemical reaction with water: None which is hazardous.

Dust explosion: Dust Electrostatic Properties:


Minimum Ignition Energy (Cloud): 25 to 30 mJ

Resistivity at Ambient Humidity: 8.17E+09 ohm.m at Humidity



59% at 22°C

Resistivity at Low Humidity: 6.18E+12 ohm.m at Humidity

4% at 23°C

Charge Relaxation Time at Ambient Humidity: < 1s at Humidity

59% at 22°C

Charge Relaxation Time at Low Humidity: 1s at Humidity


4% at 23°C



Dust Explosion Properties:

Group: A

Pmax: 8.8 bar

dP/dT: 1168 bar/s

Kst: 317 bar.m/s

St Class: 3

Limiting Oxygen: 10%

Concetration

Minimum Ignition: 560°C

Temperature-Cloud

Minimum Ignition: No ignition or exotherm observed up to
Temperature-Layer 400°C

Dust explosion determined by test: Y

Disposal considerations

Industry - Possibility of recovery/recycling: Discharge to the environment will not occur. Recovery from
minor spillages or accidental discharge is not economically
or technically feasible, and such waste material will be
disposed of by incineration. In principle, it may be
possible to recover larger spillages of uncontaminated

material for subsequent use.

Industry - Possibility of neutralisation: The notification tests have shown that the substance is
harmful by acute and prolonged oral ingestion, and there is
a possible risk of irreversible effects based on in-vivo
mutagenicity. No chemical treatment is practicable to
neutralise the hazardous health properties.



The dust hazard will be minimised by appropriate handling
and storage.


No chemical treatment is practicable to neutralise the

hazardous environmental properties.

Industry - Possibility of destruction: controlled discharge: Not recommended.

Industry - Possibility of destruction - incineration: The substance should be disposed of by incineration by
burning under controlled conditions at a licensed waste
treatment processor in accordance with local regulations.
Stack gases should be scrubbed, because noxious fumes (eg.
carbon and nitrogen oxides and halogen containing
compounds)could be formed.

Industry - Possibility of destruction - water purification: The substance should not normally be discharged directly
to the sewage system or the aqueous environment. However,
adverse effects on sewage treatment systems would be
unlikely.

Industry - Possibility of destruction - other: None.

Public at large - Possibility of recovery/recycling: Not applicable.

Public at large - Possibility of neutralisation: Not applicable.

Public at large - Possibility of destruction: controlled discharge: Not applicable.

Public at large - Possibility of destruction - incineration: Not applicable.

Public at large - Possibility of destruction - water purification: Not applicable.

Public at large - Possibility of destruction - others: None.