Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.


4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible


4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

5.2. Special hazards arising from the substance or mixture
carbon monoxide, Carbon dioxide, toxic gases/vapours, nitrous gases
The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder). Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Temperature class: T3 (Autoignition temperature >200 °C).

7.2. Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.

Suitable materials for containers: Carbon steel (Iron), Stainless steel 1.4301 (V2), Stainless steel 1.4541, Stainless steel 1.4401, Stainless steel 1.4571, glass, High density polyethylene (HDPE)

Storage class according to TRGS 510 (originally VCI, Germany): (8A) Combustible corrosive substances

Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

7.3. Specific end use(s)
See exposure scenario(s) in the attachment to this safety data sheet.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

The surveillance of the workplace by exposure measurements may be necessary, in order to proof the efficiency of safety measures, for example ventilation or the need of respiratory protection. Since this requires a specific competency, only accredited laboratories should be contracted. Regarding suitable methods for inhalative exposure assessment the European Standards EN 482, 689 and 14042 are to be considered. In addition the TRGS 402 has to be observed in Germany.

629-50-5: Tridecane
OEL 600 mg/m3 (TRGS 900 (DE))
Ceiling limit value/factor: 2
Short Term Exposure Classification: (TRGS 900 (DE))
Category II: Substances with a resorptive effect
27458-92-0: Isotridecan-1-ol
Short Term Exposure Classification: (TRGS 900 (DE)), Vapor and aerosol
Category I: Substances for which the localized effect has an assigned exposure limit or for substances with a sensitizing effect in respiratory passages
OEL 164 mg/m3 ; 20 ppm (TRGS 900 (DE)), Vapor and aerosol
Ceiling limit value/factor: 1
Sum of vapors and aerosols.

PNEC
freshwater: 0,0123 mg/l

marine water: 0,00123 mg/l

intermittent release: 0,123 mg/l

STP: 49 mg/l

sediment (freshwater): 61,3 mg/kg

sediment (marine water): 6,13 mg/kg

soil: 1 mg/kg

oral (secondary poisoning):
No PNEC value available.


DNEL
worker:
Long-term exposure- systemic effects, Inhalation: 0,850 mg/m3


8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:
chemical-protection suit (f.e. according to EN 14605)

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Take off immediately all contaminated clothing. Store work clothing separately.

Environmental exposure controls
For information regarding environmental exposure controls, see Section 6.



Occupational Exposure Limit
Type of limit MAK (DE) other: no MAK-value established

Stability and reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.


10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions
Strong exothermic reaction with acids.


10.4. Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.

10.5. Incompatible materials

Substances to avoid:
acids, nitrosating agents

10.6. Hazardous decomposition products

Possible thermal decomposition products:
carbon monoxide, Carbon dioxide
toxic gases/vapours, nitrogen oxides

Disposal considerations

Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.