Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

Remove contaminated clothing.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.

On skin contact:
Wash thoroughly with soap and water

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:
Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting unless told to by a poison control center or doctor.

Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11 of msds.

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam

Unsuitable extinguishing media for safety reasons:
water jet

Special hazards arising from the substance or mixture
Endangering substances: harmful vapours
Advice: Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.

Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Breathing protection required.

Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.

Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13 of msds.

Handling and storage

Precautions for safe handling
Protection against fire and explosion:
Heated containers should be cooled to prevent polymerization. Take precautionary measures against static discharges.

Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Protect against heat. Protect from the effects of light. Ensure adequate inhibitor and dissolved oxygen level. The stabilizer is only effective in the presence of oxygen. Maintain contact with atmosphere containing 5 - 21% oxygen.

Protect from temperatures above: 45 °C

Specific end use(s)
See exposure scenario(s) in the attachment to the msds.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains ETHOXYLATED, PROPOXYLATED PROPYLIDYNETRIMETHANOL, ESTERS WITH ACRYLIC ACID)
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
Environmental hazards: yes
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains ETHOXYLATED, PROPOXYLATED PROPYLIDYNETRIMETHANOL, ESTERS WITH ACRYLIC ACID)
Subsidiary hazard(s):
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
Environmental hazards: yes
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains ETHOXYLATED, PROPOXYLATED PROPYLIDYNETRIMETHANOL, ESTERS WITH ACRYLIC ACID)
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
Environmental hazards: yes
Marine pollutant: YES
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains ETHOXYLATED, PROPOXYLATED PROPYLIDYNETRIMETHANOL, ESTERS WITH ACRYLIC ACID)
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
Environmental hazards: yes
Remarksopen allclose all

Additional transport information

Additional information
Special provisions / remarks / other:
Not classified as a dangerous good under transport regulations

Exposure controls / personal protection

Components with occupational exposure limits
No substance specific occupational exposure limits known.

PNEC
freshwater: 0.0038 mg/l
marine water: 0.00038 mg/l
intermittent release: 0.038 mg/l
STP: 100 mg/l
sediment (freshwater): 0.0557 mg/kg
sediment (marine water): 0.00557 mg/kg
soil: 0.00889 mg/kg
STP: 100 mg/l
freshwater: 0.0038 mg/l
marine water: 0.0004 mg/l
sediment (freshwater): 1.05 mg/kg
sediment (marine water): 0.105 mg/kg
soil: 0.208 mg/kg


DNEL worker:
Long-term exposure- systemic effects, dermal: 7.6 mg/kg
worker:
Long-term exposure- systemic effects, Inhalation: 26.6 mg/m3

Exposure controls

Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:
Corrosive effects to metal are not anticipated.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
The product can polymerize if the shelf life or storage temperature are greatly exceeded. Heat develops during polymerization. Reacts with peroxides and other radical components.
The product is stabilized against spontaneous polymerization prior to despatch.

Conditions to avoid
Avoid heat. Avoid all sources of ignition: heat, sparks, open flame. Avoid direct sunlight. Avoid inhibitor loss. Avoid oxygen content above the product of less than 5 %. To maintain inhibitor activity, oxygen must not be eliminated from the atmosphere above the product.

Substances to avoid:
peroxides, free radical initiators, Inert gas

Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods

Must be disposed of or incinerated in accordance with local regulations.

The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted (United Kingdom).


Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.