Registration Dossier

Administrative data

First-aid measures

DESCRIPTION OF FIRST AID MEASURES
If inhaled:
- Remove to fresh air.
- Obtain medical attention.

In case of skin contact:
- Remove contaminated clothing and shoes.
- Wash off with warm water and soap.
- If symptoms persist, call a physician.

In case of eye contact:
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- If symptoms persist, call a physician.

If swallowed:
- Do NOT induce vomiting.
- Rinse mouth with water.
- Obtain medical attention.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
- Symptoms: Symptoms may be delayed.
- Risks: Harmful in contact with skin.

INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
- Treatment: The first aid procedure should be established in consultation with the doctor responsible for industrial medicine.

Fire-fighting measures

EXTINGUSIHING MEDIA
- Suitable extinguishing media:
Extinguishing media - large fires
Alcohol-resistant foam (on small fires)
Carbon dioxide (CO2)
Dry chemical
Water spray

- Unsuitable extinguishing media:
Water spray jet

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
- Specific hazards during firefighting:
Burning produces irritant fumes.
Exposure to decomposition products may be a hazard to health.

ADVICE FOR FIREFIGHTERS
- Special protective equipment for firefighters: Body covering protective clothing, full "turn-out" gear. Self-contained breathing apparatus (EN 133)
- Further information: Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
- Personal precautions:
Evacuate personnel to safe areas.
Avoid contact with skin and eyes.
Avoid breathing vapours, mist or gas.
Wear suitable protective equipment.

ENVIRONMENTAL PRECAUTIONS
- Environmental precautions:
Do not allow contact with soil, surface or ground water.
Do not flush into surface water or sanitary sewer system.

METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
- Methods for cleaning up: Pick up and arrange disposal without creating dust.

Handling and storage

PRECAUTIONS FOR SAFE HANDLING
- Advice on safe handling:
Handle in accordance with good industrial hygiene and safety practice.
Use plant protection products safely. Always read the label and product information before use.
Avoid contact with skin, eyes and clothing.
Wear suitable protective equipment.
Use with adequate ventilation.
Keep container tightly closed.
Avoid formation of dust and aerosols.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATABILITIES
- Requirements for storage areas and containers:
Keep in a dry, cool place.
Keep away from strong bases. Keep away from direct sunlight.

- Other data:
Stable under recommended storage conditions.

SPECIFIC END USE
- Specific use(s):
Plant protection agent
Herbicide

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Chemical name:
Dichlobenil
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Chemical name:
Dichlobenil
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Chemical name:
Dichlobenil
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., Environmentally hazardous substance, solid, n.o.s.
Chemical name:
Dichlobenil
Class:
9
Packaging group:
III
Labels:
Miscellaneous
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

CONTROL PARAMETERS
- Contains no substances with occupational exposure limit values.

EXPOSURE CONTROLS
- Personal protective equipment:

Eye protection:
Safety glasses with side-shields

Hand protection
Material: butyl-rubber
Break through time: > 480 min
Glove thickness: 0.4 mm
Protective index: Class 6
Remarks: butyl-rubber The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Before removing gloves clean them with soap and water.

Skin and body protection:
Impervious clothing

Respiratory protection:
In the case of dust or aerosol formation use respirator with an approved filter.

Filter type:
Combined particulates and organic vapour type (A-P)

Stability and reactivity

REACTIVITY
No dangerous reaction known under conditions of normal use.

CHEMICAL STABILITY
Stable under normal conditions.

POSSIBILITY OF HAZARDOUS REACTIONS
Hazardous reactions: No dangerous reaction known under conditions of normal use.

CONDITIONS TO AVOID
Conditions to avoid: Extremes of temperature and direct sunlight.

INCOMPATIBLE MATERIALS
Materials to avoid: Keep away from strong bases.

HAZARDOUS DECOMPOSITION PRODUCTS
Burning produces noxious and toxic fumes.

Disposal considerations

WASTE TREATMENT METHODS
- Product: In accordance with local and national regulations.