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Diss Factsheets

Environmental fate & pathways

Biodegradation in water: screening tests

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Description of key information

Diethyl sulphide is considered to be not readily biodegradable.

Key value for chemical safety assessment

Additional information

The potential of diethyl sulphide to biodegrade in water is read across from methyl ethyl sulphide. These substances are sulphides, characterised aliphatic thiols with a simple straight chain structure, characterised by a sulphur atom in the centre of the chain. The substances vary only by size, with methyl ethyl sulphide containing 3 carbons and diethyl sulphide containing 4 carbons. The substances have very similar sizes and structures, with a single unifying functional group, and given the similarity in physico-chemical properties, the substances are expected to have similar behaviour in the environment. The result being read across from methyl ethyl sulphide to diethyl sulphide is conservative and therefore, read across between the sulphides for biodegradation is considered to be justified.

Gancet (2011) is a GLP-compliant, ready biodegradation test performed, with methyl ethyl sulphide, according to the OECD testing guideline 301D (closed-bottle test). 41% degradation was observed after 28 days and according to these results, methyl ethyl sulphide is considered as not readily biodegradable. This is supported by Thiébaud (1999), a ready biodegradation test performed with methyl ethyl sulphide according to the OECD testing guideline 301D (closed-bottle test). 34% degradation was observed after 28 days and according to these results, methyl ethyl sulphide is considered as not readily biodegradable.