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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Emergency measure - Inhalation: Remove patient from exposure, keep warm and at rest. Obtain
medical attention if ill effects occur

Emergency measure - Eyes: Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes. Obtain medical attention.

Emergency measure - Skin: Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. If symptoms (irritation or blistering) occur obtain medical attention.

Emergency measure - Ingestion: Wash out mouth with water and give 200-300 ml of water to drink. Do NOT induce vomiting as a First-Aid measure. Obtain medical attention if ill effects occur.

Fire-fighting measures

Recommended extinguishing agent: Water spray, foam, dry powder or CO2.

Unsuitable: Avoid high pressure media which could cause the formation of a potentially explosible dust-air mixture.

Product arising from burning: If involved in a fire, it may emit noxious and toxic fumes.

Special protective actions for fire-fighters: A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Ensure suitable personal protection during removal of spillages.

Environmental Precautions: Prevent entry into drains, sewers or watercourses. Collect spillage.

Methods and material for containment and cleaning up: Moisten spillages with water. Transfer to a container for disposal. Wash the spillage area with water. Avoid release to the environment.

Handling and storage

Precaustions for safe handling: Avoid inhalation. Avoid contact with skin and eyes. Minimize dust generation and accumulation. Avoid breathing dust. Wear protective gloves. The material can form flammable dust clouds in air. The material may form explosible dust-air mixture if dispersed. Dust clouds may be extremely sensitive to ignition by electrostatic discharge and other ignition sources. Ensure good earthing of equipment and personnel.

Storage: Keep container tightly closed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-({(3AR,4S,6R,6AS)-6-[7-CHLORO-5-(PROPYLTHIO)-3H-[1,2,3]TRIAZOLO[4,5-D]PYRIMIDIN-3-yl]-2,2-DIMETHYLTETRAHYDRO-3AH-CYCLOPENTA[D][1,3]DIOXOL-4-YL}OXY)ETHANOL)
Language:
English
Labels:
9
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Shippingopen allclose all
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Marine transport (UN RTDG/IMDG)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-({(3AR,4S,6R,6AS)-6-[7-CHLORO-5-(PROPYLTHIO)-3H-[1,2,3]TRIAZOLO[4,5-D]PYRIMIDIN-3-yl]-2,2-DIMETHYLTETRAHYDRO-3AH-CYCLOPENTA[D][1,3]DIOXOL-4-YL}OXY)ETHANOL)
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3077
Shipping information
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s. (2-({(3AR,4S,6R,6AS)-6-[7-CHLORO-5-(PROPYLTHIO)-3H-[1,2,3]TRIAZOLO[4,5-D]PYRIMIDIN-3-yl]-2,2-DIMETHYLTETRAHYDRO-3AH-CYCLOPENTA[D][1,3]DIOXOL-4-YL}OXY)ETHANOL)

Labels:
9
Special provisions / remarks
Remarks:
Transport code: UN 3077
Transport: ICAO/IATA

UN No. : 3077

Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (UL125)

Class : 9

Packing Group : III

Air Pack Instruction Passenger / Cargo : 911

Air Pack Instruction Cargo Only : 911

Emergency Response Guidance Code : 9L



IMO/IMDG

UN No. : 3077

Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (UL125)

Class : 9

Marine Pollutant : Classified as a Marine Pollutant

Packing Group : III

Packing Instruction : P002

EMS Number : F-A, S-F


ADR

UN No. : 3077

Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (UL125)

Class : 9

Label(s) : 9

Classification Code : M7

Packing Group : III

Packing Instruction : P002

HIN : 90
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Exposure controls / personal protection

Exposure Controls: Atmospheric levels should be controlled using the principles of good occupational hygiene practice as specified in the workplace risk assessment.Prevent entry into drains, sewers or watercourses.

Occupational exposure controls: Decisions about whether the use of Personal Protective Equipment (PPE) is appropriate, as part of the control strategy, should be based on the workplace risk assessment and should take account of local legislative requirements for selection and use. There are multiple factors that will affect the specific requirements such as amount and concentration of the material, duration of exposure, frequency of exposure etc.

Respiratory protection: Use a negative pressure air purifying respirator (half face mask) with filter class P3 if the risk assessment does not support the selection of other protection.
Skin protection: Use impervious clothing to protect against direct contact with the substance if the risk assessment does not support the selection of other protection. Use impervious protective gloves to protect against direct contact with the substance. If the substance is dissolved or wetted use a glove material that is resistant to the solvent/liquid.
Eye protection: Use safety glasses to protect against direct contact with the substance if the risk assessment does not support the selection of other protection.

Stability and reactivity

Reactivity: No known reactivity hazard under normal conditions.
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions : None known.
Conditions to avoid: No conditions producing hazardous situations known.
Incompatible materials: None known.
Hazardous decomposition products: No hazardous decomposition products are known

Disposal considerations

Chemical Disposal Waste treatment methods: Disposal should be in accordance with local, state or national legislation. Waste, even small quantities, should never be poured down drains, sewers or water courses. This material and/or its container must be disposed of as hazardous waste. Dispose of contents/ container to an approved incineration plant.
Contaminated Packaging: Empty container will retain residue. Observe all hazard precautions.