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Physical & Chemical properties

Explosiveness

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Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2015
Report Date:
2015

Materials and methods

Test guideline
Qualifier:
according to
Guideline:
other: “Manual of Test Criteria" of “Recommendations of Dangerous Goods"; UN-Test 1 (c), 2 (c) und C.1 (Time-Pressure-Test)
Deviations:
no
GLP compliance:
no

Test material

Reference
Name:
Unnamed
Type:
Constituent
Test material form:
other: Solution
Details on test material:
ethylmagnesium bromide 45% in 2-Methyltetrahydrofuran

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
other: More sensitive to shock than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: More sensitive to friction than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
not measured/tested
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
not measured/tested
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

   Test 1  Test 2  Test 3
Net weight [g]  5,1  5,2  5,1
Time to 690 kPag [s]  -  -  30
Time to 2070 kPag [s]  -  -  -
Pressure increase time [s]  -  -  -

None of the three tests could show an increase of pressure up to 2070 kPa. Thus, according UN-Test 1(c), 2(c) und C.1 the result is negative.

UN-Tests 1(c) and 2(c)_ "-"

UN Test C.1: "no"

Applicant's summary and conclusion

Executive summary:

According to UN-Test 1(b), 2(b) and E.1 the result is negative.

UN-Tests 1(b) and 2(b): "-"

UN-Test E.1: "no"