Registration Dossier

Administrative data

First-aid measures

Description of first aid measures:
Eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Consult oculist.
Skin contact : Wash off with soap and water.
Ingestion : Rinse mouth with plenty of water. Do not induce vomiting. Consult a physician.
Inhalation : Take person to fresh air. If necessary, seek medical advice.

Most important symptoms and effects: Symptoms : Severe eye irritation. In case of eye contact: redness and pain.

Indication of immediate medical attention and special treatment needed: General advice : Call a physician immediately.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media : Alcohol-resistant foam., Carbon dioxide (CO2)., Dry extinguishing powder., Water.
Extinguishing media which must not be used for safety reasons: Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture:
Specific hazards during fire fighting: In case of fire, thermal decomposition with emission of hazardous fumes is possible
Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Advice for fire-fighters: Special protective equipment for fire-fighters : Regular fire intervention clothes.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Personal precautions : Cleanup personnel must use appropriate personal protective equipment.
Additional advice : Avoid dust formation. Avoid contact with skin and eyes. Keep away from heat and sources of ignition.

Environmental precautions: Environmental precautions : The product should not be allowed to enter drains, water courses or the soil.

Methods and material for containment and cleaning up: Methods for cleaning up : Dike the spill if necessary. Remove the dust with an suck upsystem. Avoid swirling. Collect the product in a plastic vessel. Carefully collect leftovers.

Handling and storage

Precautions for safe handling:
Advice on safe handling : Prevent product from diffusing.
Hygiene measures : Observe normal precautions when handling chemicals.Employees should wash their hands and face before eating, drinking, or using tobacco products.Keep away from foodstuffs, drinks and tobacco.
Advice on protection against fire and explosion : Keep away from heat and sources of ignition.Avoid dust formation.

Conditions for safe storage:
Requirements for storage areas and containers : Keep container tightly closed.Keep in a dry, cool place.
Further information on storage conditions : Keep container in a well-ventilated place.
Advice on common storage : No data available.

Specific end use: This substance is used only by trained professionals under restricted conditions.

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde)
Chemical name:
2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
Labelling No. : 9
Risk No. : 90
Environmentally Hazardous : Yes
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde)
Chemical name:
2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
Labelling No. : 9
Risk No. : 90
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde)
Chemical name:
2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde
Class:
9
Packaging group:
III
EmS number:
F-A, S-F
Labels:
Labelling No. : 9
Marine pollutant:
yes (P)
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s. (2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde)
Chemical name:
2-chloor-3-(hydroxymethyleen)-1-cyclohexeen-1-carboxaldehyde
Class:
9
Packaging group:
III
Labels:
Labelling No. : 9MI
Remarks
Packing instruction : 956

Additional transport information

Additional transport information
For transport by RID, the same specifications are applicable as by ADNR.

Exposure controls / personal protection

Control parameters: Components with occupational exposure limits rsp. biological occupational exposure limits requiring monitoring:

1. Occupational exposure limits:
Air limit values: Particles not otherwise classified (inhalation fraction: dust/mist): 3 mg/m³Particles not otherwise classified (inhalation fraction): 10 mg/m³
Biological limit values: We are not aware of any national exposure limit.

2. Additional exposure limits under the conditions of use: No other exposure limits applicable.

3. DNEL/DMEL and PNEC-values: No Chemical Safety Report performed. No DNEL/DMEL value determined. No PNEC value determined.


Exposure controls:

1. Occupational exposure controls:
1.1. Instruction measures to prevent exposure: Employees should wash their hands and face before eating, drinking, or using tobacco products.Keep away from foodstuffs, drinks and tobacco.
1.2. Technical measures to prevent exposure: Ensure adequate ventilation.
1.3. Personal measures to prevent exposure:
Respiratory protection : Dust mask.
Hand protection : Use chemical resistant gloves. In case of prolonged immersion or frequently repeated contact use gloves made of the materials: butylrubber (thickness >= 0.70 mm, breakthrough time > 480 min).(EN 374). The use of protective gloves should conform to the specifications of EC directive 89/686/EC and the resultant standard EN374. Additional advice: The data are based on own tests, literature data and information of glove manufacturers or derived from
similar substances. Because several factors may influence these properties (eg temperature), one should take into account the fact that the life of a chemical gloves in practice may be considerably shorter than indicated by the permeation test. The high diversity of types of use are prescribed by the manufacturer.
Eye protection : Safety goggles. EN 166.
Body Protection : Safety clothes.
Personal protective equipment : Emergency showers and eye wash stations should be available. Eye-wash bottle with clean water.

2. Environmental exposure controls:
Do not release into drain. Collect for removal by a licensed waste contractor. Effluent regulations/discharge/treatment/contents may vary from one area to another. Please consult the local regulations regarding the disposal of this material.
EU Directive Status
European Directive 2000/60/EC (water) not on list
European Directive 1996/62/EC (air) not on list

Stability and reactivity

Reactivity : Reaction or decomposition is observed in an air atmosphere as well as in a nitrogen atmosphere.
Chemical stability: Unstable at room temperature.
Possibility of hazardous reactions: Reaction or decomposition is observed in an air atmosphere as well as in a nitrogen atmosphere.
Conditions to avoid: Heat.
Materials to avoid: No data available
Hazardous decomposition products: No data available

Disposal considerations

Waste treatment methods:

Waste disposal methods: Do not release into drain. Collect for removal by a licensed waste contractor. Effluent regulations/discharge/treatment/contents may vary from one area to another. Please consult the local regulations regarding the disposal of this material.
Empty containers: As the packaging can be contaminated with product residus, please observe the warnings of the label even when the container is empty.Do not reuse empty container without proper cleaning.Label precautions also apply to this container when empty.

For waste resulting from the expired product, it is recommended to use European Waste Code : 20 01 17 (photochemicals).