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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures

General information

Seek medical assistance if discomfort continues

After inhalation

Remove the casualty into fresh air and keep him calm.

After contact with skin

In case of contact with skin, clean with soap and water. Consult a physician.

After contact with eyes

Rinse the affected eye with plenty of water, at the same time keep the unaffected eye well

protected. Consult a physician.

After ingestion

Immediately make victim drink water. Consult a physician.

4.2. Most important symptoms and effects, both acute and delayed


Irritation; applies to aromatic amines in general: methaemoglobinaemia

4.3. Indication of any immediate medical attention and special treatment needed


Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media

water spray jet


Extinguishing media that must not be used for safety reasons

Full water jet

5.2. Special hazards arising from the substance or mixture

In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)

Carbon dioxide (CO2)

Nitrogen oxides (NOx)

Hydrogen fluoride (HF)

5.3. Advice for firefighters

Special protective equipment for firefighting

Use self-contained breathing apparatus

Further information

Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

Wear protective equipment.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear suitable personal protective equipment. Do not breathe vapours, aerosols. Ensure adequate ventilation

6.2. Environmental precautions

Do not allow entry to drains, water courses or soil

6.3. Methods and material for containment and cleaning up

Collect spills and take up with liquid-absorbent material.

When picked up, treat material as prescribed under heading "Disposal considerations".

6.4. Reference to other sections

Additional information

Information regarding Safe handling, see chapter 7.

Information regarding personal protective measures see, chapter exposure controls / personal protection

Information regarding Waste Disposal, see chapter disposal considerations

Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

Do not breathe vapours and aerosols. Ensure adequate ventilation.

Advice on protection against fire and explosion

Take precautionary measures against electrostatic charges - earthing necessary during

loading operations.

Keep away from sources of ignition

Vapours form explosive mixtures with air.

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions

Keep container tightly closed in a cool, well-ventilated place, open and handle carefully.

Keep away from sources of ignition.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
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Inland waterway transport (UN RTDG/ADN(R))

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Marine transport (UN RTDG/IMDG)

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Air transport (UN RTDG/ICAO/IATA)

UN number:
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Exposure controls / personal protection

During its lifecycle the substance is handled under strictly controlled conditions and is rigorously contained in accordance Art. 18.

Based on the knowledge of the basic hazards to humans and environment technical, organizational and PPE measures are taken to minimize release and exposure of this substance. National regulatory requirements for the handling of chemicals are also fulfilled. Employees are regularly trained. The efficiency of these measures is controlled e.g. by workplace measurements. In case of deviations these measures are adapted.

8.1. Control parameters

Exposure limit values

Exposure limit values are not available.

DNEL/DMEL values

DNEL/DMEL values are not available.

PNEC values

PNEC values are not available.

8.2. Exposure controls

General protective measures

Do not inhale dust

Avoid contact with eyes and skin

Hygiene measures

Wash hands before breaks and after work.

Use barrier skin cream.

Remove soiled or soaked clothing immediately and clean thoroughly before using again.

Respiratory protection : Wear dust mask when handling large quantities

Hand protection : Chemical resistant gloves

Minimum breakthrough time (glove): not determined

Minimum thickness (glove): not determined

Observe the information of the glove manufacturers on

permeability and breakthrough times and other workplace


Eye protection : safety glasses

Body protection : working clothes

Stability and reactivity

10.1. Reactivity

See section 10.3. "Possibility of hazardous reactions"

10.2. Chemical stability

Sensitive to light and air.

10.3. Possibility of hazardous reactions

No dangerous reactions are known

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

not known

Disposal considerations

13.1. Waste treatment methods


Product should be be taken to a suitable and authorized waste disposal site in

accordance with relevant regulations and if necessary after consultation with the waste

disposal operator and/or the competent Authorities

Uncleaned packaging

Packaging that cannot be cleaned should be disposed of as product waste