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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

4.1. Description of first aid measures
General information
Seek medical assistance if discomfort continues
After inhalation
Remove the casualty into fresh air and keep him calm.
After contact with skin
In case of contact with skin, clean with soap and water. Consult a physician.
After contact with eyes
Rinse the affected eye with plenty of water, at the same time keep the unaffected eye well
protected. Consult a physician.
After ingestion
Immediately make victim drink water. Consult a physician.
4.2. Most important symptoms and effects, both acute and delayed
Irritation; applies to aromatic amines in general: methaemoglobinaemia
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media
water spray jet
Extinguishing media that must not be used for safety reasons
Full water jet
5.2. Special hazards arising from the substance or mixture
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Hydrogen fluoride (HF)
5.3. Advice for firefighters
Special protective equipment for firefighting
Use self-contained breathing apparatus
Further information
Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.
Wear protective equipment.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear suitable personal protective equipment. Do not breathe vapours, aerosols. Ensure adequate ventilation
6.2. Environmental precautions
Do not allow entry to drains, water courses or soil
6.3. Methods and material for containment and cleaning up
Collect spills and take up with liquid-absorbent material.
When picked up, treat material as prescribed under heading "Disposal considerations".
6.4. Reference to other sections
Additional information
Information regarding Safe handling, see chapter 7.
Information regarding personal protective measures see, chapter exposure controls / personal protection
Information regarding Waste Disposal, see chapter disposal considerations

Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Do not breathe vapours and aerosols. Ensure adequate ventilation.
Advice on protection against fire and explosion
Take precautionary measures against electrostatic charges - earthing necessary during
loading operations.
Keep away from sources of ignition
Vapours form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions
Keep container tightly closed in a cool, well-ventilated place, open and handle carefully.
Keep away from sources of ignition.

Transport information

Land transport (UN RTDG/ADR/RID)

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Inland waterway transport (UN RTDG/ADN(R))

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Marine transport (UN RTDG/IMDG)

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Air transport (UN RTDG/ICAO/IATA)

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Exposure controls / personal protection

During its lifecycle the substance is handled under strictly controlled conditions and is rigorously contained in accordance Art. 18.
Based on the knowledge of the basic hazards to humans and environment technical, organizational and PPE measures are taken to minimize release and exposure of this substance. National regulatory requirements for the handling of chemicals are also fulfilled. Employees are regularly trained. The efficiency of these measures is controlled e.g. by workplace measurements. In case of deviations these measures are adapted.

8.1. Control parameters
Exposure limit values
Exposure limit values are not available.
DNEL/DMEL values
DNEL/DMEL values are not available.
PNEC values
PNEC values are not available.
8.2. Exposure controls
General protective measures
Do not inhale dust
Avoid contact with eyes and skin
Hygiene measures
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.
Respiratory protection : Wear dust mask when handling large quantities
Hand protection : Chemical resistant gloves
Minimum breakthrough time (glove): not determined
Minimum thickness (glove): not determined
Observe the information of the glove manufacturers on
permeability and breakthrough times and other workplace
Eye protection : safety glasses
Body protection : working clothes

Stability and reactivity

10.1. Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2. Chemical stability
Sensitive to light and air.
10.3. Possibility of hazardous reactions
No dangerous reactions are known
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
not known

Disposal considerations

13.1. Waste treatment methods
Product should be be taken to a suitable and authorized waste disposal site in
accordance with relevant regulations and if necessary after consultation with the waste
disposal operator and/or the competent Authorities
Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste