Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

After inhalation: Supply fresh air; consult doctor in case of symptoms
After skin contact: Instantly wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing: Rinse out mouth and then drink plenty of water. Seek medical treatment

Indication of any immediate medical attention and special treatment needed: Medical supervision for at least 48 hours

Fire-fighting measures

Extinguishing media
- Suitable extinguishing agents: CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
- For safety reasons unsuitable extinguishing agents: Water with a full water jet.

Special hazards arising from the substance or mixture
- Formation of toxic gases is possible during heating or in case of fire.
- Can be released in case of fire: Hydrogen chloride (HCl) and Carbon monoxide (CO)

Advice for firefighters
- Protective equipment: Do not inhale explosion gases or combustion gases. Wear suitable protective clothing

Accidental release measures

Personal precautions, protective equipment and emergency procedures
- Wear protective clothing.
- Keep away from ignition sources
- Wear protective equipment. Keep unprotected persons away.

Environmental precautions: Do not allow to enter drainage system, surface or ground water.

Methods and material for containment and cleaning up:
- Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Handling and storage

Precautions for safe handling
- Use only in well ventilated areas.

Information about protection against explosions and fires:
- Keep ignition sources away - Do not smoke. Protect against electrostatic charges.

Conditions for safe storage, including any incompatibilities
- Requirements to be met by storerooms and containers: Store only in unopened original containers. Store the product in a cool and ventilated place, away from heat, sun exposure without sewers open.
- Information about storage in one common storage facility: Store away from foodstuffs.
- Further information about storage conditions: Keep container tightly sealed.

Transport information

Land transport (ADR/RID)

UN number:
1993
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Class:
3
Classification code:
F1 Flammable liquids
Packaging group:
III
Labels:
3
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Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (chlorocyclohexane)
Chemical name:
chlorocyclohexane
Class:
3
Packaging group:
III
EmS code:
F-E, S-E
Labels:
3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (chlorocyclohexane)

Chemical name:
chlorocyclohexane
Class:
3
Packaging group:
III
Labels:
3
Remarksopen allclose all

Additional transport information

Additional transport information
- Excepted quantities (EQ): E1
- Limited quantities (LQ): LQ7
- Transport category: 3
- Tunnel restriction code: D/E

Exposure controls / personal protection

Control parameters
- Components with limit values that require monitoring at the workplace: n.a.

Exposure controls - Personal protective equipment
- General protective and hygienic measures: Wash hands during breaks and at the end of the work.
- Breathing equipment: breathing protection recommended
- Protection of hands: Solvent resistant gloves. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
- Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
- Penetration time of glove material: The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
- Eye protection: Tightly sealed safety glasses.
- Body protection: Solvent resistant protective clothing. Boots

Stability and reactivity

Chemical stability:
- Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.

Possibility of hazardous reactions:
- No dangerous reactions known

Conditions to avoid:
- No further relevant information available.

Incompatible materials:
- No further relevant information available.

Hazardous decomposition products:
- Thermal decomposition products may include toxic and corrosive fumes of chlorides and toxic oxides of nitrogen

Disposal considerations

Waste treatment methods
- Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

Uncleaned packaging
- Recommendation: Disposal must be made according to official regulations