Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General:
Symptoms of poisoning may appear several hours later.
If you feel unwell, seek medical advice (show the label where possible).
Remove contaminated or saturated clothing immediately and dispose of safely.

Description of first aid measures:
Inhalation:
Provide fresh air, seek medical advice if necessary.

Skin Contact:
Wash with soap and water.

Eye contact:
Rinse immediately with plenty of water for 15 minutes and seek advice of an eye specialist.

Ingestion:
Flush mouth immediately, then drink plenty of water, avoid vomiting, consult physician

Most important symptoms and effects, both acute and delayed:
Sensitization Symptoms of poisoning may not appear for several hours.
Keep under medical supervision for at least 48 hours.

Indication of any immediate medical attention and special treatment needed:
Hazards:
Toxic by inhalation.

Treatment:
Treatment of symptoms.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
Water spray, foam, CO2, dry powder.

Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture:
Hazard-determining flue gases might develop in case of fire: nitrogen oxides

Advice for firefighters:
Special fire fighting procedures:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely.
Keep out unprotected persons.

Special protective equipment for fire-fighters:
Wear a self contained respiratory apparatus.
Full protective suit.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment.
Avoid formation of dust.
Ensure sufficient ventilation.
Keep unauthorized personnel away.

For non-emergency personnel:
No data available.

For emergency responders:
No data available.

Environmental Precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow to sink into ground water, sewers or into surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and material for containment and cleaning up:
Collect up material.
Transfer into suitable containers for recovery or disposal.
Disposal according to local authority regulations.
Avoid dust formation.

Reference to other sections:
Wear personal protective equipment; see section "Exposure controls / personal protection.

Handling and storage

Precautions for safe handling:
Wash hands before breaks and immediately after handling the product.
Provide sufficient ventilation and exhaust at the workplace.
When using do not eat or drink.
Do not breathe dust.
Refill and handle product only in closed system.
Avoid dust formation.
Avoid residues of the product on the containers.
Provide sufficient ventilation and exhaust at the workplace.
The personal protective equipment used must meet the requirements of Regulation (EU) 2016/425 and amendments (CE certification).

Conditions for safe storage, including any incompatibilities:
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations. Keep away from combustion sources such as sparks, flames and unprotected light sources.
When using do not smoke.
Take precautionary measures against static charges, keep away from sources of ignition.
If dusts develop, explosive dust/air mixtures may form.

Storage Class:
6.1 D: Non-combustible substances of acute toxicity, category 3 / hazardous substances that are toxic or produce chronic effects

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. (4,4'-Bismaleimidodiphenylmethane)
Chemical name:
4,4'-Bismaleimidodiphenylmethane
Language:
English
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. (4,4'-Bismaleimidodiphenylmethane)
Chemical name:
4,4'-Bismaleimidodiphenylmethane
Language:
English
Labels:
6.1
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. (4,4'-Bismaleimidodiphenylmethane)
Chemical name:
4,4'-Bismaleimidodiphenylmethane
Labels:
6.1
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s. (4,4'-Bismaleimidodiphenylmethane)
Chemical name:
4,4'-Bismaleimidodiphenylmethane
Labels:
6.1
Remarksopen allclose all

Additional transport information

Additional information
Special provisions / remarks / other:
IATA_C: ERG-Code 6L
IATA_P: ERG-Code 6L

Keep separate from foodstuffs, luxury foods, feedstuffs

Exposure controls / personal protection

Exposure controls:
Appropriate Engineering Controls:
Suitable measuring processes are: N,N-dimethylformamide
Provide appropriate exhaust ventilation at machinery.
Provide for installation of emergency shower and eye bath.
OSHA method 66
NIOSH method 2004
German Research Foundation (DFG)

Individual protection measures, such as personal protective equipment:
Eye/face protection:
Safety glasses with side-shields conforming to EN166

Hand Protection:
Material: Nitrile.
Glove thickness: 0.11 mm
Guideline: DIN EN 374

Additional Information:
Applies to handling for brief periods or of small amounts.
Material: Nitrile/Chloroprene
Glove thickness: 0.65 mm
Guideline: DIN EN 374

Additional Information:
Applies to handling for longer periods or of large amounts

Additional Information:
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.
Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).

Skin and Body Protection:
Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.

Respiratory Protection:
When handling for a short time:
Respirator with P2 particle filter In the case of respirable dust, use self-contained breathing apparatus.
Note time limit for wearing respiratory protective equipment.

Hygiene measures:
Prevent the formation of dust.
Take off immediately all contaminated clothing.
Provide adequate ventilation.
Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and at the end of workday.
Do not inhale smoke, dust, vapor.

Stability and reactivity

Reactivity:
No data available.

Chemical Stability:
No data available.

Possibility of hazardous reactions:
No dangerous reaction known under conditions of normal use. polymerisation (exothermic) with amines.

Conditions to avoid:
No decomposition if used as directed.
Take precautionary measures against static discharges.
Avoid shock and friction.

Incompatible Materials:
No further information available

Hazardous Decomposition Products:
No hazardous decomposition products known.

Disposal considerations

Waste treatment methods:
General information:
No data available.

Disposal methods:
Pack and label wastes like the pure substance.
Do not detach label from the delivery containers prior to disposal.
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
Must not be disposed of together with household wastes.
The product should not be allowed to enter drains, water courses or the soil.

Contaminated Packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.