Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 202-728-6 | CAS number: 99-08-1
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Toxicity to microorganisms
Administrative data
Link to relevant study record(s)
- Endpoint:
- toxicity to microorganisms, other
- Type of information:
- other: BUA report
- Adequacy of study:
- other information
- Reliability:
- other: BUA report
- Rationale for reliability incl. deficiencies:
- other: No reliability is given as this is a summary entry for the BUA report.
- Principles of method if other than guideline:
- BUA report
- GLP compliance:
- not specified
- Validity criteria fulfilled:
- not specified
- Executive summary:
BUA report (1989):
Among the measurements made in a study on the effect of aromatic nitrocompounds on the bioluminescence of Photobacterium phosphoreum was the mononitrotoluene concentration which causes a 50% reduction in the bacterium's glowing intensity, compared to that of the control, after exposure for 15 minutes. The EC50value for m-nitrotoluene was 3.95 mg/l (Deneer et al., 1988).
- Endpoint:
- toxicity to microorganisms, other
- Type of information:
- experimental study
- Adequacy of study:
- other information
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- documentation insufficient for assessment
- Principles of method if other than guideline:
- other: cell multiplication inhibition test
- GLP compliance:
- not specified
- Specific details on test material used for the study:
- - Name of test material (as cited in study report): m-Nitrotoluene
- Analytical purity: "analytical grade" - Analytical monitoring:
- no
- Details on test solutions:
- - Stock solution of test substance was added to the sterile medium to provide a concentration ratio
of 1.8 in 10 ml of 2 % proteose peptone.
- The solutions were then inoculated with 0.2 ml of the pre-cultured T. pyriformis and cultivated at
a temperature of 30 °C for 24 h without agitation. - Test organisms (species):
- Tetrahymena pyriformis
- Details on inoculum:
- - Tetrahymena pyriformis was preserved in a sterile medium (of 2 % proteose peptone at a temperature of 20 °C) which was renewed at 2-4 week intervals.
- Tetrahymena pyriformis was pre-cultured at a temperature of 30 °C for 24 h. - Test type:
- static
- Water media type:
- freshwater
- Limit test:
- no
- Total exposure duration:
- 24 h
- Test temperature:
- 30 °C
- Duration:
- 24 h
- Dose descriptor:
- EC50
- Effect conc.:
- 50 mg/L
- Conc. based on:
- test mat.
- Basis for effect:
- growth inhibition
- Validity criteria fulfilled:
- not specified
- Executive summary:
A cell-multiplication-inhibition test on the acute toxicity of 3-nitrotoluene to Tetrahymena pyriformis was performed for a test period of 24 hours. An EC50 value of 50 mg/l was reported (Yoshioka et al., 1985).
- Endpoint:
- toxicity to microorganisms, other
- Type of information:
- experimental study
- Adequacy of study:
- other information
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- documentation insufficient for assessment
- Principles of method if other than guideline:
- other: cell multiplication inhibition test according to Bringmann (1978)
- GLP compliance:
- no
- Specific details on test material used for the study:
- - Name of test material (as cited in study report): 3-Nitrotoluol
- Analytical purity: no data - Analytical monitoring:
- no
- Test organisms (species):
- Uronema parduzci
- Total exposure duration:
- 20 h
- Test temperature:
- 25 °C
- pH:
- 6.9 (adjusted)
- Duration:
- 20 h
- Dose descriptor:
- other: EC5
- Effect conc.:
- 24 mg/L
- Validity criteria fulfilled:
- not specified
- Executive summary:
A cell multiplication inhibition test according to Bringmann (1978) on the acute toxicity of 3-nitrotoluene to Uronema parduzci was performed for a test period of 20 hours. An EC5 value of 24 mg/l was reported (Bringmann, 1980, 1981).
- Endpoint:
- toxicity to microorganisms, other
- Type of information:
- experimental study
- Adequacy of study:
- other information
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- documentation insufficient for assessment
- Principles of method if other than guideline:
- other: cell multiplication inhibition test according to Bringmann (1978)
- GLP compliance:
- no
- Specific details on test material used for the study:
- - Name of test material (as cited in study report): 3-Nitrotoluol
- Analytical purity: no data - Analytical monitoring:
- no
- Test organisms (species):
- Chilomonas paramaecium
- Total exposure duration:
- 48 h
- Test temperature:
- 25 °C
- pH:
- 6.9 (adjusted)
- Duration:
- 48 h
- Dose descriptor:
- other: EC5
- Effect conc.:
- 48 mg/L
- Validity criteria fulfilled:
- not specified
- Executive summary:
A cell multiplication inhibition test according to Bringmann (1978) on the acute toxicity of 3-nitrotoluene to Chilomonas paramaecium was performed for a test period of 48 hours. An EC5 value of 48 mg/l was reported (Bringmann, 1980).
- Endpoint:
- toxicity to microorganisms, other
- Type of information:
- experimental study
- Adequacy of study:
- other information
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- documentation insufficient for assessment
- Principles of method if other than guideline:
- other: cell multiplication inhibition test according to Bringmann (1978)
- GLP compliance:
- no
- Specific details on test material used for the study:
- - Name of test material (as cited in study report): 3-Nitrotoluol
- Analytical purity: no data - Analytical monitoring:
- no
- Test organisms (species):
- Entosiphon sulcatum
- Details on inoculum:
- - Stock and preliminary cultures of protozoa are fed with viable bacteria (Escherichia coli).
- Total exposure duration:
- 72 h
- Test temperature:
- 25 °C
- pH:
- 6.9 (adjusted)
- Details on test conditions:
- - The number of protozoa is determined by means of a cell counter (Coulter counter) after addition of
a suitable electrolyte (10 % of a 1.1 % NaNO3 solution in double-distilled water filtered through a
membrane filter (pore size = 0.2 µm) - Duration:
- 72 h
- Dose descriptor:
- other: EC5
- Effect conc.:
- 12 mg/L
- Validity criteria fulfilled:
- not specified
- Executive summary:
A cell multiplication inhibition test according to Bringmann (1978) on the acute toxicity of 3-nitrotoluene to Entosiphon sulcatum was performed for a test period of 72 hours. An EC5 value of 12 mg/l was reported (Bringmann, 1980, 1981).
- Endpoint:
- toxicity to microorganisms, other
- Type of information:
- experimental study
- Adequacy of study:
- other information
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- documentation insufficient for assessment
- Principles of method if other than guideline:
- cell multiplication inhibition test according to Bringmann and Kuehn
- GLP compliance:
- no
- Specific details on test material used for the study:
- - Name of test material (as cited in study report): 3-Nitrotoluol
- Analytical purity: no data - Analytical monitoring:
- no
- Test organisms (species):
- Pseudomonas putida
- Total exposure duration:
- 16 h
- Test temperature:
- 25 °C
- pH:
- 7
- Duration:
- 16 h
- Dose descriptor:
- other: EC3
- Effect conc.:
- 10 mg/L
- Validity criteria fulfilled:
- not specified
- Executive summary:
A cell multiplication inhibition test according to Bringmann (1976, 1977, 1979, 1980) on the acute toxicity of 3-nitrotoluene to Pseudomonas putida was performed for a test period of 16 hours. An EC3 value of 10 mg/l was reported (Bringmann, 1976, 1977, 1979, 1980).
- Endpoint:
- toxicity to microorganisms, other
- Type of information:
- experimental study
- Adequacy of study:
- other information
- Reliability:
- 3 (not reliable)
- Rationale for reliability incl. deficiencies:
- other: Unsuitable test system; important information missing (e.g. quality criteria)
- Principles of method if other than guideline:
- Microtox test applied according to manual of analyzer (Model Toxicity Analyzer DXY-2 of the Institute of Soil Science, Academia Sinica, Nanjing)
- GLP compliance:
- not specified
- Specific details on test material used for the study:
- - Name of test material (as cited in study report): 3-Nitrotoluene
- Analytical purity: > 95% - Analytical monitoring:
- no
- Test organisms (species):
- Photobacterium phosphoreum
- Water media type:
- freshwater
- Total exposure duration:
- 15 min
- Test temperature:
- 20°C
- Duration:
- 15 min
- Dose descriptor:
- EC50
- Effect conc.:
- 24.95 mg/L
- Validity criteria fulfilled:
- not specified
- Executive summary:
A microtox test was applied according to manual of the analyzer (Model Toxicity Analyzer DXY-2 of the Institute of Soil Science, Academia Sinica, Nanjing) in order to investigate the acute toxicity of 3-nitrotoluene to Phosphobacterium phosphoreum. An EC50 (15 min) value of 24.95 mg/l was reported (Zhao, 1995).
Referenceopen allclose all
BUA report (1989):
Among the measurements made in a study on the effect of aromatic nitrocompounds on the bioluminescence of Photobacterium phosphoreum was the mononitrotoluene concentration which causes a 50% reduction in the bacterium's glowing intensity, compared to that of the control, after exposure for 15 minutes. The EC50value for m-nitrotoluene was 3.95 mg/l (Deneer et al., 1988).
Reported TT (Toxicity Threshold) is comparable to EC5; value refers to nominal TS concentration.
Reported TT (Toxicity Threshold) is comparable to EC5; value refers to nominal TS concentration.
Reported TT (Toxicity Threshold) is comparable to EC5; value refers to nominal TS concentration.
Reported TT (Toxicity threshold) is comparable to EC3; value refers to nominal TS concentration.
- Results are given in mol/l
- It is reported that also tests with an incubation period of 30 min had been performed, and that the results were similar to these performed with a 15 min incubation period
- Unfortunately method only partly described
Description of key information
For transported isolated intermediates according to REACh, Article 18, this endpoint is not a data requirement. However, data is available for this endpoint and is thus reported under the guidance of "all available data".
A cell-multiplication-inhibition test on the acute toxicity of 3-nitrotoluene to Tetrahymena pyriformis was performed for a test period of 24 hours. An EC50 value of 50 mg/l was reported (Yoshioka et al., 1985).
BUA report (1989): Among the measurements made in a study on the effect of aromatic nitrocompounds on the bioluminescence of Photobacterium phosphoreum was the mononitrotoluene concentration which causes a 50% reduction in the bacterium's glowing intensity, compared to that of the control, after exposure for 15 minutes. The EC50value for m-nitrotoluene was 3.95 mg/l (Deneer et al., 1988).
A cell multiplication inhibition test according to Bringmann (1978) on the acute toxicity of 3-nitrotoluene to Uronema parduzci was performed for a test period of 20 hours. An EC5 value of 24 mg/l was reported (Bringmann, 1980, 1981).
A cell multiplication inhibition test according to Bringmann (1978) on the acute toxicity of 3-nitrotoluene to Entosiphon sulcatum was performed for a test period of 72 hours. An EC5 value of 12 mg/l was reported (Bringmann, 1980, 1981).
A cell multiplication inhibition test according to Bringmann (1978) on the acute toxicity of 3-nitrotoluene to Chilomonas paramaecium was performed for a test period of 48 hours. An EC5 value of 48 mg/l was reported (Bringmann, 1980).
A cell multiplication inhibition test according to Bringmann (1976, 1977, 1979, 1980) on the acute toxicity of 3-nitrotoluene to Pseudomonas putida was performed for a test period of 16 hours. An EC3 value of 10 mg/l was reported (Bringmann, 1976, 1977, 1979, 1980).
A microtox test was applied according to manual of the analyzer (Model Toxicity Analyzer DXY-2 of the Institute of Soil Science, Academia Sinica, Nanjing) in order to investigate the acute toxicity of 3-nitrotoluene to Phosphobacterium phosphoreum. An EC50 (15 min) value of 24.95 mg/l was reported (Zhao, 1995).
Key value for chemical safety assessment
Additional information
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.