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Diss Factsheets
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EC number: 202-728-6 | CAS number: 99-08-1
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Oxidising properties
Administrative data
Link to relevant study record(s)
- Endpoint:
- oxidising liquids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.21 (Oxidising Properties (Liquids))
- Deviations:
- no
- GLP compliance:
- not specified
- Contact with:
- other: cellulose
- Key result
- Sample tested:
- test mixture as specified
- Remarks:
- mixtures of the sample with cellulose (ratio 1 : 1)
- Parameter:
- mean pressure rise time
- Result:
- 6 850 ms
- Remarks on result:
- other: calculated from given data (see Table below), mean, n=5
- Sample tested:
- reference mixture as specified
- Remarks:
- Reference: 65 % Nitric acid + cellulose (1 : 1 ratio)
- Parameter:
- other: pressure rise time of reference mixture
- Result:
- 2 550 ms
- Remarks on result:
- other: single value
- Interpretation of results:
- GHS criteria not met
- Remarks:
- no oxidising properties
- Conclusions:
- A test conducted according to the Guideline EC A.21 showed that the mean pressure rise time for 3-nitrotoluene (6850 ms; five run tests) was longer than the pressure rise time for the reference substance (65% nitric acid, 2550 ms; single value). Furthermore, no spontaneous ignition was observed. Therefore, 3-nitrotoluene was found to have no oxidising properties (Currenta 2009).
- Executive summary:
Heitkamp, 2009, Study No.: 2009/01371e
A test conducted according to the Guideline EC A.21 showed that the mean pressure rise time for 3-nitrotoluene (6850 ms; five run tests) was longer than the pressure rise time for the reference substance (65% nitric acid, 2550 ms; single value). Furthermore, no spontaneous ignition was observed. Therefore, 3-nitrotoluene was found to have no oxidising properties (Currenta 2009).
Reference
3 -nitrotoluene was found "not to have oxidising properties" after the following results
were obtained:
Test run | Sample amount | Maximum pressure | Time for pressure rise from 690 kPa to 2070 kPa | Remarks |
1 | 2,5 g | 2688 kPa | 6875 ms | No spontaneous ignition |
2 | 2,5 g | 2750 kPa | 5250 ms | No spontaneous ignition |
3 | 2,5 g | 2688 kPa | 8125 ms | No spontaneous ignition |
4 | 2,5 g | 2844 kPa | 7875 ms | No spontaneous ignition |
5 | 2,5 g | 2625 kPa | 6125 ms | No spontaneous ignition |
| 2,5 g | 2594 kPa | 2550 ms | Reference: 65 % Nitric acid + cellulose (1 : 1 ratio)
|
In all cases, the burning time of the m-Nitrotoluene / cellulose mixtures was found to be considerably longer than the reference mixture. Since no spontaneous ignition was observed either, m-Nitrotoluene was found to have no oxidising properties.
Description of key information
Heitkamp, 2009, Study No.: 2009/01371e
A test conducted according to the Guideline EC A.21 showed that the mean pressure rise time for 3-nitrotoluene (6850 ms; five run tests) was longer than the pressure rise time for the reference substance (65% nitric acid, 2550 ms; single value). Furthermore, no spontaneous ignition was observed. Therefore, 3-nitrotoluene was found to have no oxidising properties (Currenta 2009).
Key value for chemical safety assessment
- Oxidising properties:
- non oxidising
Additional information
Justification for classification or non-classification
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.