Registration Dossier

Administrative data

First-aid measures

GENERAL ADVICE
Take off immediately all contaminated clothing.

INHALATION
Move to fresh air.
Oxygen or artificial respiration if needed.
Consult a physician

SKIN CONTACT
Wash immediately with soap and water

EYE CONTACT
Wash well open eyes immediately, abundantly and thoroughly with water.
Consult an ophthalmologist immediately

INGESTION
Do not induce vomiting.
Seek medical advice

PROTECTION OF FIRST-AIDERS
In case of insufficient ventilation, wear suitable respiratory equipment.

Fire-fighting measures

SUITABLE EXTINGUISHING MEDIA
Water spray, foam, dry powder.

EXTINGUISHING MEDIA WHICH ARE NOT SUITABLE
All other extinguishants.

SPECIFIC METHODS
Remove all sources of ignition .
Suppress gases, fumes and/or dust with water spray jetspray

SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS
Wear self-contained breathing apparatus and protective suit.

Accidental release measures

PERSONAL PROTECTION
Avoid contact with skin, eyes and inhalation of dust.

ENVIRONMENTAL PROTECTION
Do not let the product enter into drains.
Do not contaminate surface water.

METHODS FOR CLEANING UP .
1/ Recovery
Shovel or sweep up
Recover the product and place in a dry labelled container.
2/Disposal
Destroy the product by incineration (in accordance with local and national regulations).

Handling and storage

HANDLING .
1/ Technical measures / Precautions
Storage and handling precautions applicable to products : DUST FORMING.
Provide appropriate exhaust ventilation at machinery and at places where dust can be generated
Dust may form explosive mixture in air. Provide electrical earthing of equipment. Only use safety equipment.
Provide water supplies, ocular fountains and showers near the point of use.
2/Safe handling advice
If dust is formed, wear a dust mask.

STORAGE .
1/ Technical measures / Storage conditions
Keep in a well-ventilation place. Keep in a dry place. Store protected from moisture.
2/Incompatible products
Oxidants, strong acids.

PACKAGING MATERIALS .
Recommended:Fibre drums lined with polyethylene, Polypropylene big bags

Transport information

Land transport (ADR/RID)

UN number:
2811
Proper shipping name and description:
TOXIC SOLID ORGANIC, N.O.S, (4-METHYLTHIOSEMICARBAZIDE)
Chemical name:
4-METHYLTHIOSEMICARBAZIDE
Language:
English
Class:
6.1 (9)
Packaging group:
II
Labels:
6.1 + Polluant Marin
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2811
Proper shipping name and description:
TOXIC SOLID ORGANIC, N.O.S., (4-METHYLTHIOSEMICARBAZIDE)
Chemical name:
4-METHYLTHIOSEMICARBAZIDE
Class:
6.1 (9)
Packaging group:
II
Labels:
6.1 + polluant Marin
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2811
Proper shipping name and description:
TOXIC SOLID ORGANIC, N.O.S, (4-METHYLTHIOSEMICARBAZIDE)
Chemical name:
4-METHYLTHIOSEMICARBAZIDE
Class:
6.1 (9)
Packaging group:
II
Labels:
6.1 + polluant marin
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

GENERAL PROTECTIVE MEASURES
Ensure sufficient air exchange and/or exhaust areas.

PERSONNAL PROTECTIVE EQUIPMENT
1/Respiratory protection Effective dust mask.
2/Hand protection Impervious gloves.
3/Eye protection Safety glasses.
4/Skin and body protective clothing.
5/Specific hygiene measures Maintain strict body hygiene. Avoid contact with skin, eyes and inhalation of dust.
General industrial hygiene practice. Avoid contact with skin, eyes and clothing. Avoid breathing dust
Wash hands after handling. Remove contaminated clothing and protective equipment before entering areas.

Stability and reactivity

INCOMPATIBLE PRODUCTS: Strong acids, Strong oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS : Sulphur oxides (toxic gas),Hydrogen cyanide (hydrocyanic acid), sulfuric acid, Nitrogen oxides, Carbon oxides, Methyl isothiocyanate.

Disposal considerations

DISPOSAL CONSIDERATIONS
1/ DISPOSAL OF PRODUCT Destroy the product by incineration (in accordance with local and national regulations).
2/DISPOSAL OF PACKAGING. Destroy packaging by incineration at an approved waste disposal site (in accordance with local and national regulations).