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Diss Factsheets

Environmental fate & pathways

Hydrolysis

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Administrative data

Endpoint:
hydrolysis
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: OECD 111

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 111 (Hydrolysis as a Function of pH)
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodooctane
EC Number:
218-056-1
EC Name:
1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodooctane
Cas Number:
2043-57-4
Molecular formula:
C8H4F13I
IUPAC Name:
1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodooctane
Constituent 2
Reference substance name:
Perfluorohexylethyliodide
IUPAC Name:
Perfluorohexylethyliodide
Radiolabelling:
no

Study design

Analytical monitoring:
yes
Duration of testopen allclose all
Duration:
5 d
pH:
4
Temp.:
50
Initial conc. measured:
110.4 - 163 mg/L
Duration:
5 d
pH:
7
Temp.:
50
Initial conc. measured:
110.4 - 163 mg/L
Duration:
5 d
pH:
9
Temp.:
50
Initial conc. measured:
110.4 - 163 mg/L

Results and discussion

Transformation products:
not measured
Total recovery of test substance (in %)open allclose all
% Recovery:
96.38 - 99.25
pH:
4
Temp.:
50 °C
Duration:
5 d
% Recovery:
92.26 - 98.94
pH:
7
Temp.:
50 °C
Duration:
5 d
% Recovery:
93.1 - 99.12
pH:
9
Temp.:
50 °C
Duration:
5 d
Dissipation DT50 of parent compoundopen allclose all
pH:
4
Temp.:
50 °C
DT50:
> 1 yr
pH:
7
Temp.:
50 °C
DT50:
> 1 yr
pH:
9
Temp.:
50 °C
DT50:
> 1 yr

Any other information on results incl. tables

At the three different pH, after 5 days of incubation at 50 ± 0.5°C, less than 10% of hydrolysis was found in each case. Therefore, according to the criteria given in the guideline 111, no main study was required to conclude that the half-life time of the test substance is superior at 1 year.

PERFLUOROHEXYLETHYLIODIDE : Hydrolysis: half-life time > 1 year

Applicant's summary and conclusion