Registration Dossier
Registration Dossier
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EC number: 254-447-3 | CAS number: 39430-51-8
Guidance on Safe Use
Administrative data
First-aid measures
General considerations: Immediately remove clothing contaminated with substance.
Take care of the following instructions:
- After Inhalation: In case of unconsciousness bedding and transportation in recovery position. Supply affected person with fresh air and lay down smooth
- After skin contact: Wash skin immediately with plenty of water and soap and rinse thoroughly. In case of continuing sensitation of skin consult doctor
- After eye contact: Immediately flush eyes with running water for several minutes, keeping eyelids open. In case of continuing discomfort consult doctor
- After swallowing: Do not induce vomiting, immediately seek for medical help
Fire-fighting measures
Appropriate extinguishing devices: Small fire: CO2, dry powder or water spray. Fight large fire with water spray or alcohol stable foam.
For safety reasons inappropriate extinguishing devices: full jet of water.
Particular hazards by substance, respective combustion products or resulting gases:
- Formation of toxic gases due to heating or in case of fire.
- Acetic acid.
- In case of fire formation of Chromium(VI) is possible.
- Carbon mono- and dioxide.
- Toxic metal oxide fume.
Special protective equipment: use breathing apparatus.
Further information:
Cool endangered containers with water spray.
Collect contaminated fire water separately, must not reach canalisation.
Residues of fire and contaminated fire water must be disposed according to authorities' provision
Accidental release measures
Preventive measures related to individuals:
- use breathing apparatus
- seek shelter for individuals
- use personal protective equipment. Keep unprotected individuals away.
Measures related to the environment:
- In case of reaching bodies of waters or canalisation inform responsible authorities.
- Do not let reach canalisation, bodies of water, groundwater.
- Contain gases, vapour, fog with waterspray
Techniques for cleaning and gathering:
- After spillage gather mechanically and avoid formation of dust.
- Clean scene of accident carefully; appropriate: water.
- Dispose gathered material according to provisions.
- Contaminated material must be disposed as waste according to EAK-waste keys
Additional details:
- in case of fire formation of Chromium(VI) is possible
- Consider information on handling and storage
- Consider information on personal protective equipment
- Consider information on disposal
Handling and storage
Details on safe handling:
- Avoid formation of inhalable particles
- Avoid formation of dust
- Regularly gather dusts, the formation of which is not avoid
- Use industry vacuum cleaner or central suction unit to gather dusts
- Cool and dry storing in closed containers
Details on fire and explosion prevention:
- Keep breathing apparatus ready
Details on storage:
Requirements for storage rooms and containers:
- Use only container, which are especially registered for the substance/product
Details on storage with other substances:
- Do not store together with oxidising or acid substances
- Do not store together with food
- Do not store together with water
Further details on storage conditions:
- Keep containers tightly closed
- Protect against humidity and water
- Substance is hygroscopic
Storage class: 13
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- No dangerous good according to ADR/RID
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Marine transport (UN RTDG/IMDG)
- UN number:
- No dangerous good according to IMDG
Shipping information
- Proper shipping name and description:
- No dangerous good according to IMDG
- Chemical name:
- No dangerous good according to IMDG
- Labels:
- No dangerous good according to IMDG
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- No dangerous good according to ICAO/IATA
Shipping information
- Proper shipping name and description:
- No dangerous good according to ICAO/IATA
- Chemical name:
- No dangerous good according to ICAO/IATA
- Labels:
- No dangerous good according to ICAO/IATA
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Additional transport information
Additional information
- Special provisions / remarks / other:
- Recommendation by GRACE Manufacturing GmbH & Co. KG: Cargo aircraft only
Exposure controls / personal protection
Additional details on structuring of plants: no further details, see handling and storage
Compounds with occupational treshold values, which must be controlled: no such compounds present
Additional details: Valid lists at the time of compilation served as basis
General protection- and hygiene measures:
- Keep away from food, drinks and feeding stuff
- Remove dirty and soaked clothing
- Wash hands during breaks and after work
- Avoid contact with eyes and skin
Respiratory protection:
- During short-term or low exposition use respirator; in case of intensive and long-term exposition use air circulation independent breathing apparatus
Hand protection:
- Check protective gloves before use
- Material gloves are made of must be impermeable and stable against substance/product/formulation
- Choice of gloves according to break through times, penetration rates, and degradation
- Preventive protection of skin by use of skin protection agent is recommended
Material of gloves:
- Choice of proper gloves is depending not only from material, but also from further quality criteria depending on manufacturer
- EN 388: minimum requirement performance level 1 for all groups
- Butyl rubber
- Nitrile rubber
- Recommended thickness of material: ≥ 0.35 mm
Penetration time of glove material:
- EN 420: minimum requirement performance level 1 for all groups
- Precise perforation time can be obtained from manufacturer and is to be kept
Gloves made out of the following material are inappropriate:
- gloves made out of leather
- gloves made out of thick cloth
Eye protection:
- tight fitting goggles
Body protection:
- Personal protective equipment
Stability and reactivity
Thermic decomposition / avoidable conditions:
- No thermic decomposition in case of proper use
- Do not overheat to avoid thermic decomposition
Dangerous reactions: reactions with oxidants
Dangerous decomposition products:
- Carbon mono- and dioxide
- Acetic acid
- Chromium (VI) compounds
- Metal oxide fume
Disposal considerations
Recommendation: disposal according to authorities' provision
Waste key number:
Disposal must follow legal provisions. Depending on sector and processes, EAK waste keys are assigned by waste producer and ways of disposal need to be chosen accordingly
Recommendation: Disposal according to authorities' provision
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
