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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

DESCRIPTION OF FIRST AID MEASURES

General Information
Remove contaminated soaked clothing immediately.
In the event of persistent symptoms receive medical treatment.

After inhalation
Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion.
In the event of symptoms refer for medical treatment.

After contact with skin
Remove immediately adhering matter.
Wash off immediately with soap and plenty of water.
In case of irriation consult a physician.

After contact with eyes
Rinse imediately with plenty of water, also under the eyelids, for at least 15 minutes.
If eye irritation persists, consult a specialist.

After ingestion
Rinse out mouth and give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
Induce vomiting only upon the advice of a physician.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Harmful if swallowed.
Irritating to eyes.
May cause sensitisation by skin contact.

Fire-fighting measures

EXTINGUISHING MEDIA
Suitable extinguishing media
Foam, carbon dioxide (CO2), dry chemical, water-spray.

Extinguishing media which must not be used for safety reasons
Full water jet.

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Fire may produce : Hydrogen chloride gas, carbon monoxide (CO), carbon dioxide (CO2) and nitogen oxides (NOx).
Dust may form explosive mixture in air.
Minimum ignition energy : >1000 mJ

ADVICE FOR FIREFIGHTERS
Use breathing apparatus with independent air supply.
Protective suit.

Additional information
Cool containers at risk with water spray jet.
Do not release chemically contaminated water into drains, soil or surface waters. Sufficient measures must be taken to retain water used for extinguishing.

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTVE EQUIPMENT AND EMERGENCY PROCEDURES
Respirator must be worn if exposed to dust.
Ensure adequate ventilation.
Use personal protective clothing.
Remove all sources of ignition.
Dust may form explosive mixture in air.

ENVIRONMENTAL PRECAUTIONS
Do not discharge into the drains/surface waters/ground water.

METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Pick up mechanically, avoiding dust and provide disposal in suitable recipients.

Handling and storage

PRECAUTIONS FOR SAFE HANDLING
Advice on safe handling
Keep container tightly closed.
Provide appropriate exhaust ventilation at machinery and at places where dust can be generated.
Do not breathe dust.
Avoid contact with skin, eyes and clothing.

Advice on protection against fire and explosion
Keep away from sources of ignition.
Dust may form explosive mixture in air.
Avoid formation of dust.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Requirements for storage rooms and vessels
Keep containers tightly closed in a dry, well-ventilated place.

Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (2,4-Diaminophenoxyethanol dihydrochloride)
Chemical name:
2,4-Diaminophenoxyethanol dihydrochloride
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (2,4-Diaminophenoxyethanol dihydrochloride)
Chemical name:
2,4-Diaminophenoxyethanol dihydrochloride
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (2,4-Diaminophenoxyethanol dihydrochloride)
Chemical name:
2,4-Diaminophenoxyethanol dihydrochloride
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (2,4-Diaminophenoxyethanol dihydrochloride)
Chemical name:
2,4-Diaminophenoxyethanol dihydrochloride
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all

Additional transport information

Additional transport information
Dangerous for the environment : Yes

Exposure controls / personal protection

CONTROL PARAMETERS
Additional Advice On Limit Values
Obey TLV for common dust, if applicable.

EXPOSURE CONTROLS
Occupational Exposure Controls
Ensure adequate ventilation especially in confirmed areas.

Protective And Hygiene Measures
Do not breathe dust.
Wash hands before breaks and immediately after handling the product.
When using, do not eat, drink or smoke.
Do not wear contact lenses when handling the product.

Respiratory Protection
Respirator must be worn if exposed to dust.

Hand Protection
Protective gloves resistant to chemicals made of nitrile, minimum coat thickness 0.4mm, permeation resistance (wear duration) approx. 480 minutes.
This recommendation refers exclusively to the chemical compatibility and the test conforming to EN 374 carried out under laboratory conditions.
Therefore it is necessary to adhere additionally to the recommendations given by the manufacturer of protective gloves.

Eye Protection
Eye wash bottle with pure water.
Tightly fitting goggles.

Skin Protection
Long sleeved clothing.

Stability and reactivity

REACTIVITY
No decomposition if stored and applied as directed.

CHEMICAL STABILITY
Stable under normal conditions.

POSSIBILITY OF HAZARDOUS REACTIONS
Risk of dust explosions.

CONDITIONS TO AVOID
To avoid thermal decomposition, do not overheat.
Avoid development of dust.

INCOMPATIBLE MATERIALS
No materials to be especially mentioned.

HAZARDOUS DECOMPOSITION PRODUCTS
Hydrogen chloride gas, carbon monoxide, carbon dioxide and nitrogen oxides.

Disposal considerations

WASTE TREATMENT METHODS

Advice On Disposal
Can be incinerated, when in compliance with local regulations.
Where possible recycling is preferred to disposal.

Waste disposal number of waste from residues/unused products
070704
Wastes from organic chemical processes ; wastes from the MFSU of fine chemicals and chemical products not otherwise specified ; wastes not otherwise specified. Classified as hazardous waste.

Contaminated Packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse.
Packaging that cannot be cleaned should be disposed of like the product.