Registration Dossier

Administrative data

First-aid measures

EYES: Wash immediately with plenty of water. In the event of persistent irritation, get medical advice/attention.
SKIN: Immediately take off all contaminated clothing and have a shower. In the event of persistent irritation, get medical advice/attention.
INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Do not give anything by mouth to an
unconscious person.
INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention.

Fire-fighting measures

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SUITABLE EXTINGUISHING MEDIA
The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

Accidental release measures

PERSONAL PRECAUTIONS
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to
prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in
emergency procedures.
ENVIRONMENTAL PRECAUTIONS
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
METHODS FOR CLEANING UP
Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used.
Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired.

Handling and storage

Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Wash hands after use.
Keep the product in clearly labelled containers. Store the containers sealed, in a well ventilated place, away from direct sunlight.

Transport information

Land transport (ADR/RID)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
PIPERONYL BUTOXIDE
Language:
English
Class:
9
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
PIPERONYL BUTOXIDE
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
PIPERONYL BUTOXIDE
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

HAND PROTECTION
None required.
SKIN PROTECTION
None required.
RESPIRATORY PROTECTION
None required, unless indicated otherwise in the chemical risk assessment.
EYE PROTECTION
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.
Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways.

Stability and reactivity

The product is stable in normal conditions of use and storage.
There are no particular risks of reaction with other substances in normal conditions of use.

Disposal considerations

Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this
product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
Waste transportation may be subject to ADR restrictions.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.