p-phenylenediamine

GHS

General Information

Implementation:

EU

Type of classification:

self-classification

Remarks:

The data from the SIEF does not warrant a H311, however the stricter classification will be adhered.
In addition, STOT SE Cat 1, H 370 was added since human case studies indicate that ingestion may cause severe damage to skeletal and cardiac (striated) muscles and secondary kidney damage.
No proposal for review of the harmonized classification and labelling for the substance will be submitted to a Member State Competent Authority.

Related composition

Related composition:

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Reason for no classification:

data conclusive but not sufficient for classification

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data conclusive but not sufficient for classification

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Hazard category:

Acute Tox. 3

Hazard statement:

H301: Toxic if swallowed.

Acute toxicity - dermal

Hazard category:

Acute Tox. 3

Hazard statement:

H311: Toxic in contact with skin.

Acute toxicity - inhalation

Hazard category:

Acute Tox. 3

Hazard statement:

H331: Toxic if inhaled.

Skin corrosion / irritation

Reason for no classification:

data conclusive but not sufficient for classification

Serious eye damage / eye irritation

Hazard category:

Eye Irrit. 2

Hazard statement:

H319: Causes serious eye irritation.

Respiratory sensitisation

Reason for no classification:

data lacking

Skin sensitisation

Hazard category:

Skin Sens. 1A

Hazard statement:

H317: May cause an allergic skin reaction.

Aspiration hazard

Reason for no classification:

data lacking

Reproductive toxicity

Reason for no classification:

data lacking

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Reason for no classification:

data conclusive but not sufficient for classification

Carcinogenicity

Reason for no classification:

data conclusive but not sufficient for classification

1. Specific target organ toxicity - single (STOT-SE)

Hazard category:

STOT Single Exp. 1

Hazard statement:

H370: Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Affected organs:

other: Skeletal and cardiac (striated) muscles; kidneys

1. Specific target organ toxicity - repeated (STOT-RE)

Reason for no classification:

data lacking

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Hazard category:

Aquatic Acute 1

Hazard statement:

H400: Very toxic to aquatic life.

Hazardous to the aquatic environment (long-term)

Hazard category:

Aquatic Chronic 1

Hazard statement:

H410: Very toxic to aquatic life with long lasting effects.

M-Factor acute:

1

M-Factor chronic:

100

Hazardous to the ozone layer

Reason for no classification:

data conclusive but not sufficient for classification

Labelling

Signal word:

Danger

Hazard pictogram

GHS06: skull and crossbones

GHS08: health hazard

GHS09: environment

Hazard statements

H301: Toxic if swallowed.

H311: Toxic in contact with skin.

H331: Toxic if inhaled.

H370: Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H319: Causes serious eye irritation.

H317: May cause an allergic skin reaction.

H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

P264: Wash ... thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P273: Avoid release to the environment.

P311: Call a POISON CENTER/doctor/…

P321: Specific treatment (see ... on this label).

P391: Collect spillage.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P405: Store locked up.

P501: Dispose of contents/container to ...

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

P330: Rinse mouth.

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313: If eye irritation persists: Get medical advice/attention.

P272: Contaminated work clothing should not be allowed out of the workplace.

P302+P352: IF ON SKIN: Wash with plenty of water/…

P333+P313: If skin irritation or rash occurs: Get medical advice/attention.

P363: Wash contaminated clothing before reuse.